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Structure and Properties Modulation of RMnO3 Multiferroic Materials by Average Ionic Radius at A-Site
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Shao-Min FENG, Li-Juan WANG, Jin-Long ZHU, Qing-Qing LIU, Feng-Ying LI, Chang-Qing JIN
Chinese Journal of High Pressure Physics | 2011, 25(2) : 143 - 146
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Chinese Journal of High Pressure Physics | 2011, 25(2): 143-146
Structure and Properties Modulation of RMnO3 Multiferroic Materials by Average Ionic Radius at A-Site
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Shao-Min FENG, Li-Juan WANG, Jin-Long ZHU, Qing-Qing LIU, Feng-Ying LI, Chang-Qing JIN
Affiliations
  • Institute of Physics, Chinese Academy of Sciences, Beijing 100190
Published: 2011-04-15
Outline
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The effects of internal chemical pressure produced by A-site ionic radius were investigated for the Ho1-xDyxMnO3 system. It is found that the hexagonal HoMnO3 is gradually transformed to orthorhombic perovskite structure as reducing A-site ion size, forming three regions which contain pure hexagonal phase, mixture of hexagonal and orthorhombic phases and pure orthorhombic phase respectively. Using Rietveld method, the crystal structures were refined, and moreover, the correlations between lattice parameters and unit cell volume as a function of Dy3+ ion content x were obtained. The properties of the temperature dependence of the magnetization and specific heat were also studied. It is suggested that Dy3+-doping would increase the ordering temperature T2 of rare earth elements.

RMnO3  /  phase transitions  /  multiferroic compounds
冯少敏, 王丽娟, 朱金龙, 刘清青, 李凤英, 靳常青. A位平均离子尺寸对六方RMnO3多铁化合物的结构和性能调控. 高压物理学报, 2011 , 25 (2) : 143 -146 .
Shao-Min FENG, Li-Juan WANG, Jin-Long ZHU, Qing-Qing LIU, Feng-Ying LI, Chang-Qing JIN. Structure and Properties Modulation of RMnO3 Multiferroic Materials by Average Ionic Radius at A-Site[J]. Chinese Journal of High Pressure Physics, 2011 , 25 (2) : 143 -146 .
Year 2011 volume 25 Issue 2
17
4
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  • Receive Date:2010-01-08
  • Online Date:2026-11-02
  • Published:2011-04-15
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  • Received:2010-01-08
  • Revised:2010-01-08
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    Institute of Physics, Chinese Academy of Sciences, Beijing 100190
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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