The effects of internal chemical pressure produced by A-site ionic radius were investigated for the Ho1-xDyxMnO3 system. It is found that the hexagonal HoMnO3 is gradually transformed to orthorhombic perovskite structure as reducing A-site ion size, forming three regions which contain pure hexagonal phase, mixture of hexagonal and orthorhombic phases and pure orthorhombic phase respectively. Using Rietveld method, the crystal structures were refined, and moreover, the correlations between lattice parameters and unit cell volume as a function of Dy3+ ion content x were obtained. The properties of the temperature dependence of the magnetization and specific heat were also studied. It is suggested that Dy3+-doping would increase the ordering temperature T2 of rare earth elements.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |