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Influence of B4C Content in the Iron-Based Catalyst on the Apparent Activation Energy of Boron-Doped Diamond Single Crystals
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Yuan-Pei ZHANG1, 2, He-Sheng LI1, 2, Bin TIAN1, 2, Yong-Xin QI1, 2, Lei LIU1, 2, Mu-Sen LI1, 2
Chinese Journal of High Pressure Physics | 2010, 24(5) : 338 - 342
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Chinese Journal of High Pressure Physics | 2010, 24(5): 338-342
Influence of B4C Content in the Iron-Based Catalyst on the Apparent Activation Energy of Boron-Doped Diamond Single Crystals
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Yuan-Pei ZHANG1, 2, He-Sheng LI1, 2, Bin TIAN1, 2, Yong-Xin QI1, 2, Lei LIU1, 2, Mu-Sen LI1, 2
Affiliations
  • 1.Key Laboratory of Liquid Structure and Heredity of Materials (Ministry of Education), Shandong University, Jinan 250061, China
  • 2.Shandong Engineering Research Centre for Superhard Materials, Zoucheng 273500, China
Published: 2010-10-15
Outline
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The boron-doped diamond single crystals with different boron amounts were synthesized by adding B4C in iron-based catalyst. Based on the testing data of different thermal analysis (DTA) and thermal gravity (TG) analysis during heating process, the apparent activation energies were calculated by the Kissinger method. The effect of different boron amounts on their thermal stability and oxidation resistance were analyzed in oxidation reaction. The experimental and theoretical results showed that the variation trends of the DTA and TG are consistent with that of the apparent activation energy. In the severe oxidation process, both the thermal stability and the oxidation resistance of the boron-doped diamond single crystals increase firstly and then decrease with the increasing of boron amounts.

boron-doped diamond  /  thermal analysis  /  apparent activation energy  /  iron-based catalyst
张元培, 李和胜, 田彬, 亓永新, 刘磊, 李木森. 铁基触媒中碳化硼含量对含硼金刚石单晶表观活化能的影响. 高压物理学报, 2010 , 24 (5) : 338 -342 .
Yuan-Pei ZHANG, He-Sheng LI, Bin TIAN, Yong-Xin QI, Lei LIU, Mu-Sen LI. Influence of B4C Content in the Iron-Based Catalyst on the Apparent Activation Energy of Boron-Doped Diamond Single Crystals[J]. Chinese Journal of High Pressure Physics, 2010 , 24 (5) : 338 -342 .
Year 2010 volume 24 Issue 5
16
2
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  • Receive Date:2009-06-03
  • Online Date:2026-11-02
  • Published:2010-10-15
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  • Received:2009-06-03
  • Revised:2009-09-25
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Affiliations
    1.Key Laboratory of Liquid Structure and Heredity of Materials (Ministry of Education), Shandong University, Jinan 250061, China
    2.Shandong Engineering Research Centre for Superhard Materials, Zoucheng 273500, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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