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High Temperature and High Pressure Synthesis and Study of 0212-Type Ca3Cu2O4+δCl2-y
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Da-Xiao YANG1, 2, Qing-Qing LIU1, Wei-Bo GAO1, Wen YU1, 2, Feng-Ying LI1, Chang-Qing JIN1
Chinese Journal of High Pressure Physics | 2007, 21(1) : 15 - 19
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Chinese Journal of High Pressure Physics | 2007, 21(1): 15-19
High Temperature and High Pressure Synthesis and Study of 0212-Type Ca3Cu2O4+δCl2-y
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Da-Xiao YANG1, 2, Qing-Qing LIU1, Wei-Bo GAO1, Wen YU1, 2, Feng-Ying LI1, Chang-Qing JIN1
Affiliations
  • 1.Institute of Physics, Chinese Academy of Sciences, Beijing 100080, China
  • 2.University of Science & Technology of Beijing, Beijing 100083, China
Published: 2007-03-05
Outline
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Using the apical oxygen doping mechanism, i.e. a partial substitution of divalence O for the monovalence Cl, we synthesized Ca3Cu2O4+δCl2-y with Ag2O under high temperature and high pressure. From X-ray diffraction composition analysis, we confirmed that Ca3Cu2O4+δCl2-y crystallizes into a 0212 structure. With increasing the content of Ag2O, we found that lattice parameters a shrinked but c increased. It suggested that it should be hole doping. We also investigated the temperature dependence of the electrical resistivity and DC magnetic susceptibility for two samples, but we didn't observe superconductivity. It maybe resulted from the too low density of hole carrier.

high temperature high pressure synthesis  /  apical oxygen doping  /  oxychloride cuprate
杨达晓, 刘清青, 高伟波, 于文, 李凤英, 靳常青. 0212型Ca3Cu2O4+δCl2-y化合物高温高压合成与研究. 高压物理学报, 2007 , 21 (1) : 15 -19 .
Da-Xiao YANG, Qing-Qing LIU, Wei-Bo GAO, Wen YU, Feng-Ying LI, Chang-Qing JIN. High Temperature and High Pressure Synthesis and Study of 0212-Type Ca3Cu2O4+δCl2-y[J]. Chinese Journal of High Pressure Physics, 2007 , 21 (1) : 15 -19 .
Year 2007 volume 21 Issue 1
16
3
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Article Info
  • Receive Date:2006-09-27
  • Online Date:2026-11-01
  • Published:2007-03-05
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History
  • Received:2006-09-27
  • Revised:2006-12-30
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    1.Institute of Physics, Chinese Academy of Sciences, Beijing 100080, China
    2.University of Science & Technology of Beijing, Beijing 100083, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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