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SEM Observation of Large Polymer Extended-Chain Crystals in High-Pressure Crystallized PET/PC Blends
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Jun LÜ1, Yang HE1, Liang-Bin LI2, Rui HUANG1
Chinese Journal of High Pressure Physics | 2006, 20(4) : 439 - 444
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Chinese Journal of High Pressure Physics | 2006, 20(4): 439-444
• Research Note •
SEM Observation of Large Polymer Extended-Chain Crystals in High-Pressure Crystallized PET/PC Blends
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Jun LÜ1, Yang HE1, Liang-Bin LI2, Rui HUANG1
Affiliations
  • 1.College of Polymer Materials Science and Engineering, Sichuan University, Chengdu 610065, China
  • 2.National Synchrotron Radiation Laboratory and Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China
Published: 2006-12-05
Outline
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Large polymer extended-chain crystals have an important role that cannot be replaced in the study on low dimensional systems of physics. However, the small size of polymer extended-chain crystals that formerly had to be obtained through a long time confined their effect. Adding 10%(mass fraction) PC to PET, we obtained plenty of polymer extended-chain single crystals with C axis thickness exceeding 100 μm during the study on the high-pressure crystallization behaviors of PET/PC blends with a self-made piston-cylinder apparatus. For the first time, scanning electron microscope was employed to analyze them in a deep-going way. Large extended-chain crystals with various morphologies were observed by SEM, i.e. perfect extended-chain crystals, extended-chain crystals fractured along or perpendicular to C axis, extended-chain crystals with cohesive fracture surfaces, different wedge-shaped extended-chain crystals on different fracture surfaces and bending extended-chain crystals. Some mechanisms were also put forward for the formation of the observed large crystals.

poly (ethylene terephthalate)  /  polycarbonate  /  high-pressure crystallization  /  extended-chain crystal
吕军, 何阳, 李良彬, 黄锐. 高压结晶PET/PC共混体系中大尺寸聚合物伸直链晶体的形态观察. 高压物理学报, 2006 , 20 (4) : 439 -444 .
Jun LÜ, Yang HE, Liang-Bin LI, Rui HUANG. SEM Observation of Large Polymer Extended-Chain Crystals in High-Pressure Crystallized PET/PC Blends[J]. Chinese Journal of High Pressure Physics, 2006 , 20 (4) : 439 -444 .
Year 2006 volume 20 Issue 4
18
2
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Article Info
  • Receive Date:2005-11-06
  • Online Date:2026-11-01
  • Published:2006-12-05
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  • Received:2005-11-06
  • Revised:2006-09-09
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Affiliations
    1.College of Polymer Materials Science and Engineering, Sichuan University, Chengdu 610065, China
    2.National Synchrotron Radiation Laboratory and Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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