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Stability of n-Pentane under High Pressure
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Er-Wei QIAO, Hai-Fei ZHENG
Chinese Journal of High Pressure Physics | 2005, 19(4) : 371 - 376
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Chinese Journal of High Pressure Physics | 2005, 19(4): 371-376
• Research Note •
Stability of n-Pentane under High Pressure
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Er-Wei QIAO, Hai-Fei ZHENG
Affiliations
  • Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education, Department of Geology, Peking University, Beijing 100871, China
Published: 2005-12-05
Outline
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Raman scattering spectroscopy was used to investigate stability of n-pentane in Moissanite anvil cell from 0.07 GPa up to 4.77 GPa at ambient temperature. The result shows that CH3 symmetric and asymmetric stretching vibration, CH2 symmetric and asymmetric stretching vibration and -(CH2)n - in-phase twist mode at 2 877 cm-1, 2 964 cm-1, 2 856 cm-1, 2 935 cm-1 and 1 303 cm-1, respectively, shifted to higher frequency according to quasi-linearity with pressure increase, and an abrupt visible change was taken place, indicating that it is a sort of phenomenon of freezing at overpressurization. In addition, a high-pressure transition phase may appear in crystallized n-pentane in the range of 2.84~4.77 GPa. The equilibrium freezing pressure of n-pentane is (1.90±0.05) GPa at 27 ℃ by measuring with the method of crystal-liquid coexistence.

Moissanite anvil cell  /  Raman scattering spectroscopy  /  n-pentane  /  high pressure  /  freezing at overpressurization  /  phase transition  /  equilibrium freezing pressure
乔二伟, 郑海飞. 高压下正戊烷的稳定性研究. 高压物理学报, 2005 , 19 (4) : 371 -376 .
Er-Wei QIAO, Hai-Fei ZHENG. Stability of n-Pentane under High Pressure[J]. Chinese Journal of High Pressure Physics, 2005 , 19 (4) : 371 -376 .
Year 2005 volume 19 Issue 4
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  • Receive Date:2004-09-22
  • Online Date:2026-11-01
  • Published:2005-12-05
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  • Received:2004-09-22
  • Revised:2005-03-21
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    Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education, Department of Geology, Peking University, Beijing 100871, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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