The mixing rule and the variational perturbation theory together with van der Waals one-fluid model have been used to study the equation of state of the dense fluid He+H2 mixtures with different H2∶He compositions in this work. The first-order quantum correction is included. To test the model and computational code, the isotherm of the fluid He+H2 mixtures at 300 K is calculated by using the existing α-exp-6 optimization potential parameters. The calculated isotherm for the fluid He+H2 mixtures is in agreement with the experimental data and molecular dynamics simulations. Then the equation of state of the fluid He+H2 mixtures with different He∶H2 (He∶H2=1∶1, 1∶3, 3∶1) compositions have been further investigated in the pressure range 0~60 GPa and temperature in the range 50~7000 K. Comparisons of the present results with Monte-Carlo simulations indicate that the quantum corrections for the calculation of the thermodynamic properties become significant at lower temperatures.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |