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Stability of (Mg, Fe) SiO3-Perovskite at Lower Mantle Pressure and Temperature Conditions
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Li ZHANG1, Zi-Zheng GONG1, Hong LIU1, 2, Li-Wei DENG1, Xue-Dong XUE1, Fu-Qian JING1, 3
Chinese Journal of High Pressure Physics | 2004, 18(2) : 170 - 176
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Chinese Journal of High Pressure Physics | 2004, 18(2): 170-176
• Research Note •
Stability of (Mg, Fe) SiO3-Perovskite at Lower Mantle Pressure and Temperature Conditions
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Li ZHANG1, Zi-Zheng GONG1, Hong LIU1, 2, Li-Wei DENG1, Xue-Dong XUE1, Fu-Qian JING1, 3
Affiliations
  • 1.Institute of Physics, Southwest Jiaotong University, Chengdu 610031, China
  • 2.Department of Physics, Liaoning University, Shenyang 110036, China
  • 3.Laboratory for Shock Wave and Detonation Physics Research, Institute of Fluid Physics, CAEP, Mianyang 621900, China
Published: 2004-06-05
Outline
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Shock recovery experiments of (Mg0.92, Fe0.08) SiO3 enstatite were conducted at pressure range from 60 to 110 GPa (the corresponding temperature is estimated as 2 300~4 800 K). X-ray diffraction (XRD) and infrared absorption spectra (IR) of the recovered samples indicate that: (1) The main phase of recovered samples is single-chain structure enstatite, not the perovskite structure; (2) There is no evidence for the existence of oxides SiO2 and (Mg0.92, Fe0.08) O in the recovered samples; (3) After shock compression, some peaks different from original sample were found and these differences are getting more obvious with the increasing of pressure; (4) No obviously different peaks were found between the recovered samples below 85 GPa and those above 97 GPa, from the comparison of XRD and IR spectra among these samples. Combined with the former analysis of experiments of Hugoniot equation of state of enstatite, it was considered that enstatite transformed into perovskite structure under shock compression. The microanalysis requires retrogressive transformation of shocked samples during the process of pressure release. Especially, there is no possibility for the chemical decomposition reaction of (Mg0.92, Fe0.08) SiO3 to oxides SiO2 and (Mg0.92, Fe0.08) O occurring under shock compression, so the high-pressure phase of enstatite-perovskite structure remains stable at the experimental conditions. Meanwhile, we attribute the spectra difference between original sample and recovered samples to a crystal distortion under shock compression or release process and the loading process more probably resulted in such distortion. The results of this investigation provide basic physical evidence for the minerals composition model and the interpretation of seismic wave data for the lower mantle.

enstatite  /  shock recovery  /  XRD and IR microanalysis  /  stability of (Mg, Fe) SiO3-perovskite  /  lower mantle
张莉, 龚自正, 刘红, 邓力维, 薛学东, 经福谦. 下地幔温压下(Mg,Fe)SiO3钙钛矿的相稳定性——对冲击回收样品的微观分析. 高压物理学报, 2004 , 18 (2) : 170 -176 .
Li ZHANG, Zi-Zheng GONG, Hong LIU, Li-Wei DENG, Xue-Dong XUE, Fu-Qian JING. Stability of (Mg, Fe) SiO3-Perovskite at Lower Mantle Pressure and Temperature Conditions[J]. Chinese Journal of High Pressure Physics, 2004 , 18 (2) : 170 -176 .
Year 2004 volume 18 Issue 2
24
2
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  • Receive Date:2003-07-16
  • Online Date:2026-10-31
  • Published:2004-06-05
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  • Received:2003-07-16
  • Revised:2003-10-15
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Affiliations
    1.Institute of Physics, Southwest Jiaotong University, Chengdu 610031, China
    2.Department of Physics, Liaoning University, Shenyang 110036, China
    3.Laboratory for Shock Wave and Detonation Physics Research, Institute of Fluid Physics, CAEP, Mianyang 621900, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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