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Raman Spectroscopic Studies on Methanol as Pressure Gauge
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Er-Wei QIAO, Hai-Fei ZHENG, Qiang SUN
Chinese Journal of High Pressure Physics | 2004, 18(4) : 368 - 373
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Chinese Journal of High Pressure Physics | 2004, 18(4): 368-373
• Research Note •
Raman Spectroscopic Studies on Methanol as Pressure Gauge
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Er-Wei QIAO, Hai-Fei ZHENG, Qiang SUN
Affiliations
  • Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education, School of Earth and Space Science, Peking University, Beijing 100871, China
Published: 2004-12-05
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This paper mainly studies Raman spectroscopy of C—H stretching vibrational mode of methanol at 2 835 cm-1 from 169.2 up to 713.8 MPa under the temperature of 301 K using cubic zirconium oxide Anvil Cell. The result shows that methanol is stable at the experimental pressure, and the Raman shift of methanol at 2 835 cm-1 shows a linear dependence with pressure. The correlation between pressure and frequency shift of the 2 835 cm-1 Raman line of methanol is described by p=-3.508 9·[(Δνp)2 835]2 + 135.17 (Δνp)2 835+54.397, where 0.1<p (MPa) ≤ 713.8. So methanol can be used as a reliable pressure gauge in high hydrostatic experiments.

cubic zirconium oxide anvil cell  /  methanol  /  high pressure  /  Raman spectroscopy  /  pressure gauge
乔二伟, 郑海飞, 孙樯. 甲醇作为压标的拉曼研究. 高压物理学报, 2004 , 18 (4) : 368 -373 .
Er-Wei QIAO, Hai-Fei ZHENG, Qiang SUN. Raman Spectroscopic Studies on Methanol as Pressure Gauge[J]. Chinese Journal of High Pressure Physics, 2004 , 18 (4) : 368 -373 .
Year 2004 volume 18 Issue 4
25
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  • Receive Date:2003-07-21
  • Online Date:2026-10-31
  • Published:2004-12-05
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  • Received:2003-07-21
  • Revised:2004-05-18
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    Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education, School of Earth and Space Science, Peking University, Beijing 100871, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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