The characteristics of the CH4-CO2-H2O fluid at high temperature were studied by Raman spectroscopy. The results show that the Raman spectra of CH4 and CO2 do not influence each other, but they are both affected by H2O at high temperature. The hydrogen bonding of water decreases linearly before it becomes homogenous under isochoric condition. As the fluid becomes a homogenous gas, the Raman spectroscopy has little change with temperature. The hydrogen bonding of water, however, still remains in the homogenous liquid, even at the highest temperature of 520 ℃ in experiment. For the homogenous fluid at the highest temperature of 580 ℃ during measurement, the hydrogen bonding of liquid water remains relatively stronger.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |