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Morphology Investigation of the Extended-Chain Crystals in High-Pressure Crystallized Poly (Ethylene Terephthalate)-(Bisphenol-A) Polycarbonate Blends
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Jun LÜ1, 2, Rui HUANG2, Liang-Bin LI3
Chinese Journal of High Pressure Physics | 2010, 24(1) : 6 - 14
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收藏切换
Chinese Journal of High Pressure Physics | 2010, 24(1): 6-14
Morphology Investigation of the Extended-Chain Crystals in High-Pressure Crystallized Poly (Ethylene Terephthalate)-(Bisphenol-A) Polycarbonate Blends
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Jun LÜ1, 2, Rui HUANG2, Liang-Bin LI3
Affiliations
  • 1.Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China
  • 2.College of Polymer Materials Science and Engineering, Sichuan University, Chengdu 610065, China
  • 3.National Synchrotron Radiation Lab and Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China
Published: 2010-02-15
Outline
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Morphologies of extended-chain crystals with different characteristics, i.e. wedge-shaped crystals, bent crystals and wedge-shaped bent crystals, were disclosed with scanning electron microscopy (SEM) and atomic force microscope (AFM) in the high-pressure crystallized poly (ethylene terephthalate)/bisphenol-A polycarbonate (PET-PC) blends. The observations revealed that the thickening growth for the large polyester extended-chain single crystals should first undergo the nucleation step leading to the folded-chain nuclei, and then, the chain extension process which is an isothermal thickening resulting from transesterification and sliding diffusion. The morphological structures shed light on the fundamental nature of the large single crystals in the blends, which may be instructive to grow such large crystals in similar polymer systems.

crystal morphology  /  extended-chain crystal  /  high pressure  /  melt growth  /  polymer
吕军, 黄锐, 李良彬. 聚对苯二甲酸乙二醇酯-双酚A型聚碳酸酯共混体系中聚合物伸直链晶体的形态分析. 高压物理学报, 2010 , 24 (1) : 6 -14 .
Jun LÜ, Rui HUANG, Liang-Bin LI. Morphology Investigation of the Extended-Chain Crystals in High-Pressure Crystallized Poly (Ethylene Terephthalate)-(Bisphenol-A) Polycarbonate Blends[J]. Chinese Journal of High Pressure Physics, 2010 , 24 (1) : 6 -14 .
Year 2010 volume 24 Issue 1
32
6
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Article Info
  • Receive Date:2009-01-20
  • Online Date:2026-10-30
  • Published:2010-02-15
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  • Received:2009-01-20
  • Revised:2009-09-30
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Affiliations
    1.Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China
    2.College of Polymer Materials Science and Engineering, Sichuan University, Chengdu 610065, China
    3.National Synchrotron Radiation Lab and Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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