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Synthesis and Electric Transport Properties of Na-Filled CoSb3 at High-Pressure
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Nan DONG, Xiao-Peng JIA, Tai-Chao SU, Yi-Ping JIANG, Jian-Gang GUO, Le DENG, Hong-An MA
Chinese Journal of High Pressure Physics | 2009, 23(1) : 42 - 45
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Chinese Journal of High Pressure Physics | 2009, 23(1): 42-45
Synthesis and Electric Transport Properties of Na-Filled CoSb3 at High-Pressure
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Nan DONG, Xiao-Peng JIA, Tai-Chao SU, Yi-Ping JIANG, Jian-Gang GUO, Le DENG, Hong-An MA
Affiliations
  • National Laboratory of Superhard Materials, Jilin University, Changchun 130012, China
Published: 2009-02-15
Outline
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Skutterudite compounds Na-filled CoSb3 were successfully synthesized at high-pressure using powders of Co, NaN3 and Sb as starting materials. The X-ray diffraction (XRD) results indicate that all samples have the single phase CoSb3. No secondary phase is found when Na content wNa≤80%. The composition-dependent electric transport properties of Na-filled CoSb3 have been studied at room temperature. The Seebeck coefficient decreases with increasing Na content. The electrical resistivity decreases with increasing Na content. In this study, the obtained maximum power factor reaches 8.72 μW·cm-1·K-2 when Na content is 40%.

CoSb3  /  NaN3  /  high-pressure synthesis  /  thermoelectic materials
董楠, 贾晓鹏, 宿太超, 姜一平, 郭建刚, 邓乐, 马红安. Na填充型方钴矿化合物CoSb3的高压合成及电输运特性研究. 高压物理学报, 2009 , 23 (1) : 42 -45 .
Nan DONG, Xiao-Peng JIA, Tai-Chao SU, Yi-Ping JIANG, Jian-Gang GUO, Le DENG, Hong-An MA. Synthesis and Electric Transport Properties of Na-Filled CoSb3 at High-Pressure[J]. Chinese Journal of High Pressure Physics, 2009 , 23 (1) : 42 -45 .
Year 2009 volume 23 Issue 1
36
8
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Article Info
  • Receive Date:2008-03-01
  • Online Date:2026-10-30
  • Published:2009-02-15
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  • Received:2008-03-01
  • Revised:2008-06-18
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    National Laboratory of Superhard Materials, Jilin University, Changchun 130012, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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