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Effect of Collophanite on Removal of Low-Concentration Phosphorus in Water
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Linlin RU1, Tianhu CHEN1, Xuehua ZOU1, Dong CHEN1, Haibo LIU1, Yuhui LIU1, Shoucheng ZHU2
Journal of the Chinese Ceramic Society | 2021, 49(8) : 1776 - 1784
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Journal of the Chinese Ceramic Society | 2021, 49(8): 1776-1784
• Research Article •
Effect of Collophanite on Removal of Low-Concentration Phosphorus in Water
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Linlin RU1, Tianhu CHEN1, Xuehua ZOU1, Dong CHEN1, Haibo LIU1, Yuhui LIU1, Shoucheng ZHU2
Affiliations
  • 1.Laboratory of Nano minerals and Environmental Materials, School of Resources and Environmental Engineering, Hefei University of Technology, Hefei 230009, China
  • 2.Key Laboratory of Wastewater Purification and Ecological Restoration Materials in Anhui Province, Hefei 230009, China
  • RU Linlin (1997-), female, Master candidate. E-mail:

About Author:

RU Linlin (1997-), female, Master candidate. E-mail:

Published: 2021-08-20 doi: 10.14062/j.issn.0454-5648.20200967
Outline
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Collophanite fluorapatite particles were prepared as seed crystals with Ca2+ and F- ions, which were used to deeply purify low-concentration soluble inorganic phosphorus in water. The effects of combined reactants, reactant concentration, solution pH value and coexisting ions on the removal efficiency of phosphorus in water were investigated. To characterize the properties and clarify the mechanism of collophanite to remove soluble phosphates in water, the samples before and after pickling and phosphorus removal were characterized by scanning electron microscopy, transmission electron microscopy, thermoanalysis and Fourier transform infrared spectroscopy. Collophanite fluorapatite with calcium and fluorine exhibits the maximum phosphorus removal performance. The addition of Ca2+ ions significantly enhances the phosphorus removal efficiency, and F- ions with a low concentration have a slight effect on the phosphorus removal efficiency. Therefore, F- ions can be replaced by Ca2+ ions. When the initial concentration of phosphorus is 2 mg/L, pH value is > 6, and Ca2+ ions concentration is > 30 mg/L, the residual phosphorus concentration after the treatment is lower than 0.05 mg/L, thus meeting the Class Ⅱ standard of environmental tuality of water resource.

collophanite  /  apatite  /  crystal seed  /  depth phosphorus removal  /  phosphorus recovery
汝琳琳, 陈天虎, 邹雪华, 陈冬, 刘海波, 刘玉慧, 朱守成. 胶磷矿氟磷灰石对水中低浓度磷的去除作用. 硅酸盐学报, 2021 , 49 (8) : 1776 -1784 . DOI: 10.14062/j.issn.0454-5648.20200967
Linlin RU, Tianhu CHEN, Xuehua ZOU, Dong CHEN, Haibo LIU, Yuhui LIU, Shoucheng ZHU. Effect of Collophanite on Removal of Low-Concentration Phosphorus in Water[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (8) : 1776 -1784 . DOI: 10.14062/j.issn.0454-5648.20200967
Year 2021 volume 49 Issue 8
24
7
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Article Info
doi: 10.14062/j.issn.0454-5648.20200967
  • Receive Date:2020-12-26
  • Online Date:2026-10-30
  • Published:2021-08-20
Article Data
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History
  • Received:2020-12-26
  • Revised:2021-01-11
Funding
Affiliations
    1.Laboratory of Nano minerals and Environmental Materials, School of Resources and Environmental Engineering, Hefei University of Technology, Hefei 230009, China
    2.Key Laboratory of Wastewater Purification and Ecological Restoration Materials in Anhui Province, Hefei 230009, China

Corresponding:

CHEN Tianhu (1962-), male, Ph. D, Professor. E-mail:
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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