Zinc indium sulfide (ZnIn2S4)/MIL-125 composites were synthesized by a two-step hydrothermal method. The effect of ZnIn2S4 on the phase, morphology, chemical state, spectral response and photocatalytic performance of the composite was evaluated in detail. The results show that a small amount of ZnIn2S4 results in the morphological evolution of MIL-125 from discoid block to pie shape, and a gradual decrease of the specific surface area. The photocatalytic degradation activity towards rhodamine B dye is greatly improved at the optimal ratio of 0.8% (in mole fraction). The degradation efficiency for the composite is 97.7% while the degradation efficiency for pure MIL-125 is only 70.3% within 50 min. It is indicated that a small amount of ZnIn2S4 suppresses the carrier recombination and improves the carrier transport, finally resulting in the enhancement of photocatalytic activity. In addition, the possible mechanism is also proposed.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |