TANG Ruifeng (1992-), male, Doctoral candidate. E-mail: tangruifeng@emails.bjut.edu.cn
The hybrid effect of citric acid with polycarboxylate water-reducing agent (PCE) on the fluidity, setting time and mortar strength of high belite sulphoaluminate (HB-CSA) cement paste was investigated. The results show that citric acid with PCE prolongs the setting time of HB-CSA cement, but reduces the initial fluidity and early strength of the cement, and has no adverse effect on the later strength of the cement. The mechanism of citric acid with PCE to delay the early hydration of HB-CSA cement was analyzed by cement hydration microcalorimeter, X-ray diffractor and scanning electron microscope, and the adsorption behavior of citric acid with PCE in the early stage of hydration of HB-CSA cement was analyzed via organic carbon adsorption. It is indicated that the combined use of citric acid and PCE could delay the hydration heat release rate of the cement, inhibit the formation of ettringite, the early hydration product of cement, and change ettringite as a main hydration product of HB-CSA cement in the early stage. The morphology changes from rod-like or tubular to fine needle-like. The use of citric acid with PCE will produce a competitive adsorption in cement, thus reducing the effect of PCE dispersion in HB-CSA cement and cement fluidity.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |