KE Yan (1989-), male, Ph.D.; E-mail: keyan@issp.ac.cn
CHEN Bin (1986-), male, Ph.D., Associate Professor. bchen@issp.ac.cn
Cellulose acetate (CA) nanofibers were embedded with aggregated silver-nanocubes (AgNCs) by a coaxial electrospinning method. AgNCs were dispersed with CA and acetone-dimethylacetamide (DMAc) as a precursor solution, and AgNCs aggregation was induced with acetone. The nanofibers have a remarkable surface-enhanced Raman scattering (SERS) activity due to the strong plasmon coupling between neighboring AgNCs, which is 4 times of the monomeric-AgNC/CA sample. As a result, 0.1 nmol/L p-aminothiophenol (p-ATP) and 10 nmol/L methyl parathion can be identified, respectively. The nanofibers generate large-area homogeneous SERS signals with a relative signal deviation of less than 12% over 1 mm×1 mm area due to the homogeneous adsorption of target molecules. It is thus indicated that aggregated-AgNCs/CA nanofibers have a promising potential in SERS-based detection of organic pollutants in aqueous solutions.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |