ZHANG Jiye (1980-), male, Professor. E-mail: jychang@shu.edu.cn
Thermoelectric materials as novel clean energy materials have application prospects in waste-heat recovery and solid-state refrigeration. The thermoelectric compounds evolve from simple unitary- or binary-component crystalline systems to multinary complex systems. Among them, the multinary diamond-like compounds, the compounds with distinct sublattice and chemical bond hierarchy characteristics and their derivatives exhibit a complex crystalline-amorphous hybrid behavior in an atomic scale and present some transport effects, providing a prospect for the exploration of effects of electrical-thermal transport and systems of thermoelectric materials. This review summarized recent research progress on thermoelectric materials in sublattice engineering, including the structural design of novel "quasi-crystalline" thermoelectric compounds, the optimization of thermoelectric property and the characterization of microstructures in a sublattice scale. In addition, the relationship between the crystalline-semi-crystalline sublattice structure and the thermoelectric property of the compound was also discussed.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |