WANG Yujia (1988-), female, Master. E-mail: fsyzww@126.com
The flake structure SAPO-34 was firstly synthesized via a hydrothermal method with co-template triethylamine and tetraethylammonium bromide as crystal seeds, and then the layered SAPO-34 molecular sieves with different thicknesses were synthesized via changing the template composition. The prepared samples were characterized by X-ray diffraction, scanning electronic microscopy and NH3-temperature programmed desorption. The methanol to olefins catalytic performance of the SAPO-34 was evaluated by a fixed-bed reactor. The results show that the crystallization time of SAPO-34 shortens by to 36 h and the SAPO-34 cannot be produced without template. The template has an influence on the thickness of layered SAPO-34. The lamellar SAPO-34 has better light olefins selectivity than the flake and cubic ones, but its catalytic stability is slightly inferior to that of the flake one.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |