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Effect of Template Composition on Structure and Methanol to Olefins Catalytic Performance of SAPO-34 Molecular Sieve
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Yujia WANG1, 2, Lu LI1, Yingzhi BAI1, Min WEI1, Haiyan WANG1, 2
Journal of the Chinese Ceramic Society | 2020, 48(7) : 1128 - 1133
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Journal of the Chinese Ceramic Society | 2020, 48(7): 1128-1133
• Research Articles •
Effect of Template Composition on Structure and Methanol to Olefins Catalytic Performance of SAPO-34 Molecular Sieve
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Yujia WANG1, 2, Lu LI1, Yingzhi BAI1, Min WEI1, Haiyan WANG1, 2
Affiliations
  • 1.Liaoning Shihua University, Fushun 113001, Liaoning, China
  • 2.China University of Petroleum (East China), Qingdao 266555, Shandong, China
  • WANG Yujia (1988-), female, Master. E-mail:

About Author:

WANG Yujia (1988-), female, Master. E-mail:

Published: 2020-07-20 doi: 10.14062/j.issn.0454-5648.2020.07.20190727
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The flake structure SAPO-34 was firstly synthesized via a hydrothermal method with co-template triethylamine and tetraethylammonium bromide as crystal seeds, and then the layered SAPO-34 molecular sieves with different thicknesses were synthesized via changing the template composition. The prepared samples were characterized by X-ray diffraction, scanning electronic microscopy and NH3-temperature programmed desorption. The methanol to olefins catalytic performance of the SAPO-34 was evaluated by a fixed-bed reactor. The results show that the crystallization time of SAPO-34 shortens by to 36 h and the SAPO-34 cannot be produced without template. The template has an influence on the thickness of layered SAPO-34. The lamellar SAPO-34 has better light olefins selectivity than the flake and cubic ones, but its catalytic stability is slightly inferior to that of the flake one.

layered SAPO-34  /  seed crystal  /  light olefins  /  reaction life
王钰佳, 李璐, 白英芝, 魏民, 王海彦. 模板剂组成对SAPO-34分子筛结构和甲醇制烯烃性能的影响. 硅酸盐学报, 2020 , 48 (7) : 1128 -1133 . DOI: 10.14062/j.issn.0454-5648.2020.07.20190727
Yujia WANG, Lu LI, Yingzhi BAI, Min WEI, Haiyan WANG. Effect of Template Composition on Structure and Methanol to Olefins Catalytic Performance of SAPO-34 Molecular Sieve[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (7) : 1128 -1133 . DOI: 10.14062/j.issn.0454-5648.2020.07.20190727
Year 2020 volume 48 Issue 7
27
7
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Article Info
doi: 10.14062/j.issn.0454-5648.2020.07.20190727
  • Receive Date:2019-11-06
  • Online Date:2026-10-29
  • Published:2020-07-20
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History
  • Received:2019-11-06
  • Revised:2019-12-24
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Affiliations
    1.Liaoning Shihua University, Fushun 113001, Liaoning, China
    2.China University of Petroleum (East China), Qingdao 266555, Shandong, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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