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Kinetics Activated Magnesium Metal Batteries Based on Conversion Reaction
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Wenlong LIU1, 2, Kexian HUANG1, Xuejun ZHOU1, Chilin LI1, 2
Journal of the Chinese Ceramic Society | 2020, 48(7) : 978 - 989
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Journal of the Chinese Ceramic Society | 2020, 48(7): 978-989
• Special Issue on New-type Battery •
Kinetics Activated Magnesium Metal Batteries Based on Conversion Reaction
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Wenlong LIU1, 2, Kexian HUANG1, Xuejun ZHOU1, Chilin LI1, 2
Affiliations
  • 1.State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
  • 2.Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

    • LIU Wenlong (1998-), male, Master candidate; E-mail:

    HUANG Kexian (1996-), female, Master candidate.

About Author:

LIU Wenlong (1998-), male, Master candidate; E-mail:

HUANG Kexian (1996-), female, Master candidate.

Published: 2020-07-20 doi: 10.14062/j.issn.0454-5648.20200041
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Compared to magnesium metal batteries (MMBs) based on pure Mg2+ electrolyte, the MMBs based on hybrid electrolyte containing Mg2+ and Li+ possess some advantages such as long cycle life, fast charge and discharge processes, high Coulomb efficiency and more choices of cathode materials. The energy density of MMBs can be improved especially when conversion-based cathode materials are used. Recent development on dual-salt magnesium batteries based on conversion reaction or multiple electron transfer process was reviewed based on the aspects of sulfide and organic cathode materials. With the assistance of nano-structure regulation, conductive network construction, and ion pillaring, Mg-S and Mg-rhodizonate batteries are able to achieve a high energy density (i.e., 500 W·h/kg based on active cathode material) and a long-term cycle stability. This review proposed an additive salt strategy to accelerate the kinetics of MMBs based on conversion reaction, and provided some fresh insights for the future development of magnesium-based batteries.

magnesium battery  /  lithium-magnesium dual-salt electrolyte  /  kinetic activation  /  cathode material  /  conversion reaction
刘文龙, 黄可贤, 周学俊, 李驰麟. 动力学激活的转换型镁金属电池. 硅酸盐学报, 2020 , 48 (7) : 978 -989 . DOI: 10.14062/j.issn.0454-5648.20200041
Wenlong LIU, Kexian HUANG, Xuejun ZHOU, Chilin LI. Kinetics Activated Magnesium Metal Batteries Based on Conversion Reaction[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (7) : 978 -989 . DOI: 10.14062/j.issn.0454-5648.20200041
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Year 2020 volume 48 Issue 7
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Article Info
doi: 10.14062/j.issn.0454-5648.20200041
  • Receive Date：2020-01-20
  • Online Date：2026-10-29
  • Published：2020-07-20
Article Data
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History
  • Received：2020-01-20
  • Revised：2020-02-24
Funding
Affiliations
    1.State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
    2.Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding:

LI Chilin (1980-), male, Ph.D., Professor. E-mail:
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表12种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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