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Syntheses, Crystal Structures, and Magnetic Properties of Bimetallic Complex [Fe(2,2'-bpy)2Ni(CN)4]n
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Shuxin CUI1, Wenwen ZHANG1, Jinming SHEN1, Liying RU1, Yu ZHAO1, Bao XU2, Minghui ZUO1
Journal of the Chinese Ceramic Society | 2020, 48(6) : 919 - 924
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Journal of the Chinese Ceramic Society | 2020, 48(6): 919-924
• Research Paper •
Syntheses, Crystal Structures, and Magnetic Properties of Bimetallic Complex [Fe(2,2'-bpy)2Ni(CN)4]n
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Shuxin CUI1, Wenwen ZHANG1, Jinming SHEN1, Liying RU1, Yu ZHAO1, Bao XU2, Minghui ZUO1
Affiliations
  • 1.College of Chenical Engineering, Mudanjiang Normal University, Mudanjiang 157011, Heilongjiang, China
  • 2.College of Mathematics, Jilin Normal University, Siping 136000, Jilin, China

    • CUI Shuxin (1978-), female, Ph.D., Professor. E-mail:

About Author:

CUI Shuxin (1978-), female, Ph.D., Professor. E-mail:

Published: 2020-06-20 doi: 10.14062/j.issn.0454-5648.20190530
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A complex [Fe(2,2'-bpy)2Ni(CN)4]n (1) was synthesized with K3[Fe(CN)6] as a source of cyanide anions and Fe2+ cations, 2,2'-bipyridine (2,2'-bpy) and Ni(Ac)2·4H2O under hydrothermal condition. Based on the X-ray crystallographic studies, two cations Fe2+ and Ni2+ are alternately bridged by some cyanide ligands to form a 1D zigzag chain with 2,2'-bpy terminal ligands in complex 1. The thermogravimetric analysis shows that a bimetallic complex [Fe(2,2'-bpy)2Ni(CN)4]n has a good thermal stability. The magnetic measurement reveals an intense antiferromagnetic interaction between iron and nickel ions in complex 1.

bimetallic complex  /  iron ion  /  nickel ion  /  cyanide  /  magnetism
崔术新, 张文文, 沈金铭, 茹莉莹, 赵宇, 徐宝, 左明辉. 铁镍双金属配合物[Fe（2，2'-bpy）2Ni（CN）4]n的合成、晶体结构及磁性. 硅酸盐学报, 2020 , 48 (6) : 919 -924 . DOI: 10.14062/j.issn.0454-5648.20190530
Shuxin CUI, Wenwen ZHANG, Jinming SHEN, Liying RU, Yu ZHAO, Bao XU, Minghui ZUO. Syntheses, Crystal Structures, and Magnetic Properties of Bimetallic Complex [Fe(2,2'-bpy)2Ni(CN)4]n[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (6) : 919 -924 . DOI: 10.14062/j.issn.0454-5648.20190530
Appendix
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Year 2020 volume 48 Issue 6
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6
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Article Info
doi: 10.14062/j.issn.0454-5648.20190530
  • Receive Date：2019-07-24
  • Online Date：2026-10-29
  • Published：2020-06-20
Article Data
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History
  • Received：2019-07-24
  • Revised：2019-10-11
Funding
Affiliations
    1.College of Chenical Engineering, Mudanjiang Normal University, Mudanjiang 157011, Heilongjiang, China
    2.College of Mathematics, Jilin Normal University, Siping 136000, Jilin, China
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表12种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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