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Impact of Deficiency of A-site Cations on Structure and Piezoelectric Properties of Lead-free (NaBi)0.47Ba0.06TiO3 Ceramics
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Chunyang SU, Xiangping JIANG, Chao CHEN, Junming LIU, Xiang XIA, Xin NIE, Xiaokun HUANG, Junsheng ZHUANG
Journal of the Chinese Ceramic Society | 2020, 48(6) : 849 - 854
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Journal of the Chinese Ceramic Society | 2020, 48(6): 849-854
• Research Paper •
Impact of Deficiency of A-site Cations on Structure and Piezoelectric Properties of Lead-free (NaBi)0.47Ba0.06TiO3 Ceramics
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Chunyang SU, Xiangping JIANG, Chao CHEN, Junming LIU, Xiang XIA, Xin NIE, Xiaokun HUANG, Junsheng ZHUANG
Affiliations
  • Jiangxi Key Laboratory of Advanced Ceramic Materials, Department of Material Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333001, Jiangxi, China

    • SU Chunyang (1994-), male, Master. E-mail:

About Author:

SU Chunyang (1994-), male, Master. E-mail:

Published: 2020-06-20 doi: 10.14062/j.issn.0454-5648.20190648
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A series of nonstoichiometric (NaBi)0.47Ba0.06TiO3 (NBT-6BT) ceramics were prepared by the conventional solid-state method. The impact of A-site nonstoichiometry on the structural and electrical properties of the prepared ceramics was investigated. The room temperature diffraction patterns and Raman spectra revealed the coexistence of the Cc and P4bm phases for all samples. The experimental results in the present work showed that a deficiency in the Bi3+ and Na+ contents could lead to a transformation from the Cc to P4bm phase in addition to a variation in the piezoelectric coefficient d33 with the Cc phase fraction. Favorable thermostability for the piezoelectric properties of the ceramics was observed by testing the depolarization temperature (Td). Among them, the d33 of the N0.32B0.32T-6BT ceramics still had a value of 23 pC/N at 160 ℃. These results showed that a deficiency in the Na+ and Bi3+ contents can significantly enhance Td and extend the temperature region for the application of NBT-6BT ceramics.

lead-free ceramic  /  sodium bismuth titanate  /  structure  /  depolarization temperature
苏春阳, 江向平, 陈超, 刘俊明, 夏翔, 聂鑫, 黄枭坤, 庄俊生. A位阳离子缺位对（NaBi）0.47Ba0.06TiO3无铅压电陶瓷结构和性能的影响. 硅酸盐学报, 2020 , 48 (6) : 849 -854 . DOI: 10.14062/j.issn.0454-5648.20190648
Chunyang SU, Xiangping JIANG, Chao CHEN, Junming LIU, Xiang XIA, Xin NIE, Xiaokun HUANG, Junsheng ZHUANG. Impact of Deficiency of A-site Cations on Structure and Piezoelectric Properties of Lead-free (NaBi)0.47Ba0.06TiO3 Ceramics[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (6) : 849 -854 . DOI: 10.14062/j.issn.0454-5648.20190648
Appendix
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Year 2020 volume 48 Issue 6
27
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Article Info
doi: 10.14062/j.issn.0454-5648.20190648
  • Receive Date：2019-09-23
  • Online Date：2026-10-29
  • Published：2020-06-20
Article Data
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History
  • Received：2019-09-23
  • Revised：2019-10-27
Funding
Affiliations
    Jiangxi Key Laboratory of Advanced Ceramic Materials, Department of Material Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333001, Jiangxi, China

Corresponding:

JIANG Xiangping (1964-), male, Ph.D., Professor. E-mail:
CHEN Chao (1983-), male, Ph.D., Associate Professor.
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表12种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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