YIN Jun (1986-), male, Lecturer. E-mail: yinminghan@163.com
Poly (2-hydroxyethyl methacrylate) grafted silica (SiO2) nanoparticles (SiO2-g-PHEMA NPs) were prepared via surface-initiated activators regenerated by electron transfer atom transfer radical polymerization. Then the synthesized NPs were utilized as a hydrophilic additive for fabrication polyethersulfone (PES)/SiO2-g-PHEMA organic-inorganic composite membranes. The transmission electron microscope results confirm that the SiO2-g-PHEMA NPs uniformly dispersed in the casting solution and tend to migrate toward the membrane top surfaces. As a result, the hydrophilicity of the composite membranes is significantly improved (the contact angle decreases from 84.5° to 71.9°). The membrane exhibits the highest pure water flux and oil flux around 208.68 L/(m2·h) and 86.86 L/(m2·h) when the SiO2-g-PHEMA dosage is 1% (in mass), the pure water flux and oil flux of the unmodified PES membrane around 64.10 L/(m2·h) and 11.09 L/(m2·h). Compared to the unmodified PES membrane, the flux recovery ratio increases from 45.74% to 78.32%, suggesting the fouling-resistance of the composite membranes is greatly improved. Furthermore, the SiO2-g-PHEMA NPs exhibit good stability due to the physical intertwisting interaction between the PHEMA chains and PES chains, indicating that this material has a potential application prospect.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |