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ZIF-67 and Its Mother Liquor Derived Co3O4 as Catalyst Precursors for Hydrolysis of Ammonia Borane to Generate Hydrogen
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Lei WEI, Hongyan LIU, Dongsheng WANG, Qian WANG, Liwen MA
Journal of the Chinese Ceramic Society | 2020, 48(3) : 455 - 462
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Journal of the Chinese Ceramic Society | 2020, 48(3): 455-462
ZIF-67 and Its Mother Liquor Derived Co3O4 as Catalyst Precursors for Hydrolysis of Ammonia Borane to Generate Hydrogen
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Lei WEI, Hongyan LIU, Dongsheng WANG, Qian WANG, Liwen MA
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  • College of Chemistry and Materials Science, Langfang Normal University, Langfang 065000, Hebei, China

    • WEI Lei (1986-), male, Ph.D., Associate Professor.. E-mail:

About Author:

WEI Lei (1986-), male, Ph.D., Associate Professor.. E-mail:

Published: 2020-03-20 doi: 10.14062/j.issn.0454-5648.20190273
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ZIF-67 as one kind of zeolitic imidazolate frameworks was synthesized by a conventional precipitation method, and the mother liquor was concentrated and crystallized to recover cobalt-based compounds. For AB hydrolysis, two kinds of Co3O4 catalyst precursors (i.e., Co3O4-S and Co3O4-L) were prepared from the ZIF-67 and recovered compounds via calcination treatment, respectively. The morphology and phase composition of the samples were characterized by field-emission scanning electron microscopy and X-ray diffraction, respectively. Effects of AB and catalyst concentration and reaction temperature on the hydrogen generation rates and kinetics were investigated. The results show that Co3O4-S has a porous and polyhedral structure, and Co3O4-L is composed of nanoparticles. In addition, increasing AB and catalyst concentration can enhance the hydrogen generation rates. The maximum hydrogen production rates do not decline in the presence of Co3O4-S, but decrease to 78% of the initial level in the presence of Co3O4-L after recycling for four times.

metal-organic frameworks  /  cobalto-cobaltic oxide  /  ammonia borane  /  catalytic hydrolysis  /  hydrogen production
魏磊, 刘洪燕, 王东升, 王茜, 马丽文. ZIF-67及其母液衍生Co3O4催化氨硼烷水解制氢. 硅酸盐学报, 2020 , 48 (3) : 455 -462 . DOI: 10.14062/j.issn.0454-5648.20190273
Lei WEI, Hongyan LIU, Dongsheng WANG, Qian WANG, Liwen MA. ZIF-67 and Its Mother Liquor Derived Co3O4 as Catalyst Precursors for Hydrolysis of Ammonia Borane to Generate Hydrogen[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (3) : 455 -462 . DOI: 10.14062/j.issn.0454-5648.20190273
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Year 2020 volume 48 Issue 3
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doi: 10.14062/j.issn.0454-5648.20190273
  • Receive Date：2019-04-24
  • Online Date：2026-10-29
  • Published：2020-03-20
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  • Received：2019-04-24
  • Revised：2019-05-05
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    College of Chemistry and Materials Science, Langfang Normal University, Langfang 065000, Hebei, China
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表12种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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