LIANG Cen (1994-), female, Master candidate. E-mail: 515919465@qq.com
In this paper, new lead-free luminescent ferroelectric materials, (Bi0.5Na0.5)0.935-xSmxBa0.065Ti1-xSbxO3 (BNT-0.065BT-xSmSb) ceramics, were prepared by introducing Sm/Sb. The influence of Sm/Sb on the phase structure, microstructure and electrical functions of BNT-0.065BT was systematically studied. BNT-0.065BT-xSmSb ceramics presented a pure perovskite phase structure. Doping with Sm/Sb induced a ferroelectric to relaxor phase transformation and thus promoted strain improvement. When x=0.004, the unipolar strain was 0.31% (70 kV/cm), equivalent to a large signal d33*(Smax/Emax) of 443 pm/V. Moreover, studies on the luminescence properties showed that BNT-0.065BT-xSmSb ceramics exhibited bright orange-red luminescence under 407 nm excitation. The luminescence intensity increased as the Sm/Sb doping concentration increased. The main emission peak was a strong red emission peak located near 599 nm, corresponding to the 4G5/2→6H7/2 transition. As multifunctional materials, BNT-0.065BT-xSmSb ceramics showed great latent capacity for optical-electrical integration and coupling device applications.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |