MA Aiqiong (1970-), female, Ph.D., Professor. E-mail: maaiqiong@xauat.edu.cn
Graphitic carbon nitride (g-C3N4) nanosheet was synthesized by a facile fabrication method. Melamine was treated by a thermal polycondensation process. Pure g-C3N4 was treated by acid etching, heat etching and coupling with NH4Cl. The crystalline structure, morphology, specific surface area, band structure and visible absorption of the material were evaluated by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy analysis, X-ray photoelectron spectroscopy, Raman spectroscopy, specific surface area (BET analysis), ultraviolet visible diffuse reflection spectroscopy and Mott-Schottky curve analysis, respectively. The photocatalytic activity was estimated by the degradation of Rhodamine and tetracycline hydrochloride solution under visible light irradiation. The results show that a clear, ordered, 2D nanosheet g-C3N4 structure with a layer thickness of 47 nm is formed, and the maximum specific surface area is a maximum (22 m2/g) when the mole ratio of melamine to NH4Cl is 5∶4. The photocatalytic performance of bulk g-C3N4 is enhanced after treatment. The photocatalytic degradation rate of the sample treated with melamine and NH4Cl at a ratio of 5∶4 is 3.4 times greater than that of untreated g-C3N4. The sample degrades 83.2% tetracycline hydrochloride solution for 4 h.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |