HU Jiangkui (1994-), male, Doctoral candidate. E-mail: 1319849472@qq.com
Solid-state lithium batteries with solid electrolytes are expected to enhance the battery safety and energy density as one of the most promising next-generation batteries. Among various solid-state electrolytes, sulfide solid electrolyte is considered as promising candidate due to its ultra-high ionic conductivity. However, its large-scale production is restricted due to its fragility and difficulty in processing, which affects its application in solid-state batteries. Recent work indicates that the flexibility of solid electrolytes can be realized via introducing flexible polymers or supporting frameworks in solid electrolytes membranes, constituting a solution to the embrittlement challenge in large-scale and thin-film electrolyte preparations. Therefore, developing flexible solid electrolytes is one of the important strategies to promote the industrialization of solid-state batteries. This review introduced the physical/chemical properties and development of sulfide solid electrolytes, summarized the related research work on polymer self-supporting method and flexible skeleton-supporting method in the flexibility of solid electrolytes, and discussed the technical characteristics and advantages/disadvantages of wet/dry processes in the flexible sulfide solid electrolyte preparation, respectively. In addition, the future development aspects were also given to promote the practical application of solid-state lithium batteries.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |