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Na0.67Fe0.5Mn0.5O2 Cathode Material for Sodium Ion Battery with Modified Waste LiCoO2
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Xianglong HOU, Xuyong FENG, Yijian XU, Chenhua WU, Jian MA, Peng YE, Hongfa XIANG
Journal of the Chinese Ceramic Society | 2022, 50(1) : 16 - 25
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Journal of the Chinese Ceramic Society | 2022, 50(1): 16-25
• Research Articles •
Na0.67Fe0.5Mn0.5O2 Cathode Material for Sodium Ion Battery with Modified Waste LiCoO2
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Xianglong HOU, Xuyong FENG, Yijian XU, Chenhua WU, Jian MA, Peng YE, Hongfa XIANG
Affiliations
  • School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China
  • HOU Xianglong (1994-), male, Doctoral candidate. E-mail:

About Author:

HOU Xianglong (1994-), male, Doctoral candidate. E-mail:

Published: 2022-01-20 doi: 10.14062/j.issn.0454-5648.20210682
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Different amounts of LiCoO2 from waste lithium-ion batteries were dissolved in nitrite acid and the recovered Li and Co were used to modify Na0.67Fe0.5Mn0.5O2 cathode by a sol-gel method. Based on the results by X-ray diffraction, Li+/Co3+ ions were doped into Na0.67Fe0.5Mn0.5O2, with the smaller lattice parameters. The results by X-ray photoelectron spectroscopy show that the doping of Li/Co ions leads to the conversion of Mn3+ ions to Mn4+ ions, resulting in the less Jahn teller effect. The results by electrochemical tests indicate that the cycle stability and rate performance of the modified Na0.67Fe0.5Mn0.5O2 improve due to LiCoO2 modification. The sample with x of 0.105 (i.e., Na0.53Li0.105Co0.105(Fe0.5Mn0.5)0.79O2) possesses a capacity retention of 67% after 150 cycles at a current density of 1 C, and a specific capacity is 30 mA·h/g at 5 C.

waste lithium-ion batteries  /  lithium cobalt oxide  /  recycling and reuse  /  sodium ion batteries  /  sodium iron manganese oxide
侯香龙, 冯绪勇, 徐义俭, 吴辰华, 马健, 叶鹏, 项宏发. 废旧LiCoO2改性钠离子电池Na0.67Fe0.5Mn0.5O2正极材料. 硅酸盐学报, 2022 , 50 (1) : 16 -25 . DOI: 10.14062/j.issn.0454-5648.20210682
Xianglong HOU, Xuyong FENG, Yijian XU, Chenhua WU, Jian MA, Peng YE, Hongfa XIANG. Na0.67Fe0.5Mn0.5O2 Cathode Material for Sodium Ion Battery with Modified Waste LiCoO2[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (1) : 16 -25 . DOI: 10.14062/j.issn.0454-5648.20210682
Year 2022 volume 50 Issue 1
10
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Article Info
doi: 10.14062/j.issn.0454-5648.20210682
  • Receive Date:2021-08-13
  • Online Date:2026-10-22
  • Published:2022-01-20
Article Data
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History
  • Received:2021-08-13
  • Revised:2021-09-01
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Affiliations
    School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China

Corresponding:

XIANG Hongfa (1981-), male, Ph.D., Professor. E-mail: (XIANG Hongfa)
FENG Xuyong (1986-), male, Ph.D., Professor. (FENG Xuyong)
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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