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Enhancement of Electrochemical Performance of Polyoxyethylene-Polycaprolactone Blended Na-Ion Solid Electrolyte by Incorporating g-C3N4
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Weizhe WANG1, Ruifeng SONG1, Tong LI2, Ruonan XU1, Yuanchun ZHAO2, Long ZHANG1
Journal of the Chinese Ceramic Society | 2022, 50(1) : 47 - 54
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Journal of the Chinese Ceramic Society | 2022, 50(1): 47-54
• Research Articles •
Enhancement of Electrochemical Performance of Polyoxyethylene-Polycaprolactone Blended Na-Ion Solid Electrolyte by Incorporating g-C3N4
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Weizhe WANG1, Ruifeng SONG1, Tong LI2, Ruonan XU1, Yuanchun ZHAO2, Long ZHANG1
Affiliations
  • 1.Clean Nano Energy Center, State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, Hebei, China
  • 2.State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, Hebei, China

    • WANG Weizhe (1996-), male, Master candidate. E-mail:

About Author:

WANG Weizhe (1996-), male, Master candidate. E-mail:

Published: 2022-01-20 doi: 10.14062/j.issn.0454-5648.20210641
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The composite polymer solid electrolytes (CPE) were prepared by a solution-casting and hot-pressing method. Na-β-Al2O3 and g-C3N4 particles were incorporated into a polyoxyethylene and polycaprolactone blended polymer electrolyte to obtain the CPE. The microstructures, chemical and electrochemical properties of the composite electrolytes were investigated. The composite electrolyte with a high conductivity at room temperature, a high voltage stability, and a dendrite suppression capability is obtained via optimizing the mass ratio of each component, especially g-C3N4. At 50 ℃, the symmetric cells with metallic Na electrodes exhibit a good long-term cycling stability at a current density of 0.1 mA/cm2. The all-solid-state cells with Na3V2(PO4)3@C positive electrode and Na/C composite negative electrode maintain a specific capacity of about 107 mA·h/g at 0.2 C.

composite polymer electrolyte  /  polymer blending  /  aluminium oxide electrolyte  /  graphitic carbon nitride  /  sodium battery
王维哲, 宋瑞丰, 李彤, 徐若楠, 赵元春, 张隆. g-C3N4增强聚氧化乙烯-聚己内酯共混钠离子固态电解质电化学性能. 硅酸盐学报, 2022 , 50 (1) : 47 -54 . DOI: 10.14062/j.issn.0454-5648.20210641
Weizhe WANG, Ruifeng SONG, Tong LI, Ruonan XU, Yuanchun ZHAO, Long ZHANG. Enhancement of Electrochemical Performance of Polyoxyethylene-Polycaprolactone Blended Na-Ion Solid Electrolyte by Incorporating g-C3N4[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (1) : 47 -54 . DOI: 10.14062/j.issn.0454-5648.20210641
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Year 2022 volume 50 Issue 1
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Article Info
doi: 10.14062/j.issn.0454-5648.20210641
  • Receive Date：2021-08-05
  • Online Date：2026-10-22
  • Published：2022-01-20
Article Data
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History
  • Received：2021-08-05
  • Revised：2021-09-09
Funding
Affiliations
    1.Clean Nano Energy Center, State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, Hebei, China
    2.State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, Hebei, China

Corresponding:

ZHANG Long (1980-), male, Ph.D., Professor. E-mail:
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小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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