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Effect of Addition Agents on Artistic Glaze Derived from Purple Clay and Its Color-forming Mechanism
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Fen WANG, Yaorui HAO, Pei SHI, Pu CHEN, Boxin QIU, Pengju LIU
Journal of the Chinese Ceramic Society | 2022, 50(3) : 759 - 768
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Journal of the Chinese Ceramic Society | 2022, 50(3): 759-768
• Research Articles •
Effect of Addition Agents on Artistic Glaze Derived from Purple Clay and Its Color-forming Mechanism
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Fen WANG, Yaorui HAO, Pei SHI, Pu CHEN, Boxin QIU, Pengju LIU
Affiliations
  • School of Materials Science and Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science and Technology, Xi'an 710021, China
  • WANG Fen (1959-), female, Ph.D., Professor. E-mail:

About Author:

WANG Fen (1959-), female, Ph.D., Professor. E-mail:

Published: 2022-03-20 doi: 10.14062/j.issn.0454-5648.20210261
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A glaze with a good quality and a unique decorative pattern was prepared with purple clay as a source of iron, Ca3(PO4)2 and SnO2. The effect of addition agents on the glaze color, microstructure and artistic textures was investigated by ultraviolet-visible spectroscopy, X-ray diffraction and scanning electron microscopy, and the color mechanism was analyzed. The results illustrate that the introduction of addition agents changes the chemical state of iron, and contributes to the formation of blue fancy glaze. The introduction of Ca3(PO4)2 can cause the partial reduction of iron ions, leading to the glaze appearing blue and yellow, and Ca2+ ions promoting the separation of liquid phase to produce blue patterns. Also, the introduction of Ca3(PO4)2 and SnO2 for the increased reducibility of iron ions can increase the ratio of Fe2+ and Fe3+ ions, resulting in the glaze being blue-green, and the greater pattern and lightness value L*. The presence of Fe3+—O—Fe2+ in the vitreous is one of the color factors. The liquid separation forming the structure of the color is the auxiliary color of glaze color. The combined chemical color with structural color on the glaze becomes more colorful.

purple clay  /  addition agents  /  art glaze  /  coloring mechanism
王芬, 郝瑶睿, 施佩, 陈璞, 邱柏欣, 刘鹏举. 添加剂对紫砂土艺术色釉的影响及其呈色机理. 硅酸盐学报, 2022 , 50 (3) : 759 -768 . DOI: 10.14062/j.issn.0454-5648.20210261
Fen WANG, Yaorui HAO, Pei SHI, Pu CHEN, Boxin QIU, Pengju LIU. Effect of Addition Agents on Artistic Glaze Derived from Purple Clay and Its Color-forming Mechanism[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (3) : 759 -768 . DOI: 10.14062/j.issn.0454-5648.20210261
Year 2022 volume 50 Issue 3
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doi: 10.14062/j.issn.0454-5648.20210261
  • Receive Date:2021-04-13
  • Online Date:2026-10-22
  • Published:2022-03-20
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  • Received:2021-04-13
  • Revised:2021-06-10
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    School of Materials Science and Engineering, Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science and Technology, Xi'an 710021, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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