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Effect of Glass Network Structure on Optical Properties of CsPbI3 Perovskite Quantum Dots Glass
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Jinhua YAN1, Jiazhi XIA1, Tao CHEN1, Tao MAN2, Zhousu XU1, Xiaofeng LIU3, Hang ZHANG1, Jianrong QIU2
Journal of the Chinese Ceramic Society | 2022, 50(4) : 975 - 982
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Journal of the Chinese Ceramic Society | 2022, 50(4): 975-982
• Research Articles •
Effect of Glass Network Structure on Optical Properties of CsPbI3 Perovskite Quantum Dots Glass
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Jinhua YAN1, Jiazhi XIA1, Tao CHEN1, Tao MAN2, Zhousu XU1, Xiaofeng LIU3, Hang ZHANG1, Jianrong QIU2
Affiliations
  • 1.Institute of Intelligent Optoelectronic Technology, Zhejiang University of Technology, Hangzhou 310014, China
  • 2.College of Optical Science and Engineering, Zhejiang University, Hangzhou 310027, China
  • 3.School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China

    • YAN Jinhua (1979-), male, Ph.D., associate Professor. E-mail:

About Author:

YAN Jinhua (1979-), male, Ph.D., associate Professor. E-mail:

Published: 2022-04-20 doi: 10.14062/j.issn.0454-5648.20210934
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CsPbI3 quantum dots doped borosilicate glasses were prepared by a high-temperature melting-heat treatment technology with Cs2O, PbI2 and NaI as precursors. According to the results by X-ray diffraction and transmission electron microscopy, CsPbI3 quantum dots are precipitated in the glass substrate. The emission peak and absorption edge appear a red shift, the photoluminescence intensity and quantum yield firstly increase and then decrease, and the photoluminescence decay lifetime of quantum dots gradually increases with increasing the heat-treatment temperature or B2O3 concentration. Also, the two-dimensional (2D) network structure in the glass increases, and the mobility of Cs+, Pb2+ and I- ions increases with the increase of B2O3 concentration, which is beneficial for the precipitation of CsPbI3 quantum dots and the passivation of surface defect. The tunable red light emission of CsPbI3 quantum dots doped borosilicate glass could have potential applications in the visible band lasers and white light-emitting diodes (LED).

quantum dots  /  glass network structure  /  borosilicate glass  /  crystallization
严金华, 夏家志, 陈涛, 满涛, 许周速, 刘小峰, 张航, 邱建荣. 玻璃网络结构对CsPbI3钙钛矿量子点玻璃光学性质的影响. 硅酸盐学报, 2022 , 50 (4) : 975 -982 . DOI: 10.14062/j.issn.0454-5648.20210934
Jinhua YAN, Jiazhi XIA, Tao CHEN, Tao MAN, Zhousu XU, Xiaofeng LIU, Hang ZHANG, Jianrong QIU. Effect of Glass Network Structure on Optical Properties of CsPbI3 Perovskite Quantum Dots Glass[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (4) : 975 -982 . DOI: 10.14062/j.issn.0454-5648.20210934
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Year 2022 volume 50 Issue 4
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Article Info
doi: 10.14062/j.issn.0454-5648.20210934
  • Receive Date：2021-11-02
  • Online Date：2026-10-22
  • Published：2022-04-20
Article Data
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History
  • Received：2021-11-02
  • Revised：2021-11-22
Funding
Affiliations
    1.Institute of Intelligent Optoelectronic Technology, Zhejiang University of Technology, Hangzhou 310014, China
    2.College of Optical Science and Engineering, Zhejiang University, Hangzhou 310027, China
    3.School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding:

XU Zhousu (1981-), male, Ph.D., associate Professor. E-mail:
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表12种不同金属材料的力学参数
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Number of
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小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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