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Effect of High-Entropy Boride Content on Microstructure and Mechanical Properties of Silicon Nitride Ceramics
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Ruilin LIN, Qiankun GU, Sichun LUO, Yan ZHANG, Weiming GUO, Huatai LIN
Journal of the Chinese Ceramic Society | 2022, 50(6) : 1499 - 1503
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Journal of the Chinese Ceramic Society | 2022, 50(6): 1499-1503
• Research Articles •
Effect of High-Entropy Boride Content on Microstructure and Mechanical Properties of Silicon Nitride Ceramics
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Ruilin LIN, Qiankun GU, Sichun LUO, Yan ZHANG, Weiming GUO, Huatai LIN
Affiliations
  • School of Electromechanical Engineering, Guangdong University of Technology, Guangzhou 510006, China
  • LIN Ruilin (1997-), male, Master candidate. E-mail:

About Author:

LIN Ruilin (1997-), male, Master candidate. E-mail:

Published: 2022-06-20 doi: 10.14062/j.issn.0454-5648.20210901
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Silicon nitride (Si3N4) ceramics have a wide potential application in industrial processes, but high fracture toughness and hardness are always difficult to be handled, thus affecting the application of Si3N4 ceramics. In this paper, silicon nitride ceramics were fabricated via spark plasma sintering at 1 600 ℃ with high-entropy boride phase (Hf0.2Zr0.2Ta0.2Cr0.2Ti0.2)B2 as sintering aids. The effect of (Hf0.2Zr0.2Ta0.2Cr0.2Ti0.2)B2 on the phase assemblage, densification, microstructure and mechanical properties was investigated. Compared with (Hf0.2Zr0.2Ta0.2Cr0.2Ti0.2)B2-free Si3N4 ceramic, the addition of only 1.0% (in volume fraction) (Hf0.2Zr0.2Ta0.2Cr0.2Ti0.2)B2 in the ceramic can increase the mass fraction of β-Si3N4 from 38% to 53% at 1 600 ℃, showing a bimodal microstructure. As a consequence, the fracture toughness of Si3N4-based ceramic increases from (5.4±0.3) MPa·m1/2 to (6.9±0.2) MPa·m1/2, and the hardness maintains (20.2±0.2) GPa. The relative density of Si3N4-based ceramics decreases and the phase transformation enhances with increasing the high-entropy boride fraction to 2.5% and 5.0%, thus leading to a decrease in the hardness.

silicon nitride ceramic  /  high-entropy boride  /  phase assemblage  /  microstructure  /  mechanical properties
林锐霖, 顾乾坤, 罗嗣春, 张岩, 郭伟明, 林华泰. 高熵硼化物含量对Si3N4陶瓷显微结构与性能的影响. 硅酸盐学报, 2022 , 50 (6) : 1499 -1503 . DOI: 10.14062/j.issn.0454-5648.20210901
Ruilin LIN, Qiankun GU, Sichun LUO, Yan ZHANG, Weiming GUO, Huatai LIN. Effect of High-Entropy Boride Content on Microstructure and Mechanical Properties of Silicon Nitride Ceramics[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (6) : 1499 -1503 . DOI: 10.14062/j.issn.0454-5648.20210901
Year 2022 volume 50 Issue 6
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Article Info
doi: 10.14062/j.issn.0454-5648.20210901
  • Receive Date:2021-10-21
  • Online Date:2026-10-22
  • Published:2022-06-20
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History
  • Received:2021-10-21
  • Revised:2022-01-06
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Affiliations
    School of Electromechanical Engineering, Guangdong University of Technology, Guangzhou 510006, China

Corresponding:

GUO Weiming (1982-), male, Ph.D., Professor. E-mail:
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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