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Preparation of Superhydrophilic-Superoleophobic Diatomite Porous Ceramics and Its Oil-Water Emulsion Continuous Separation Performance
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Lei HAN, Xiaojian LI, Faliang LI, Haijun ZHANG
Journal of the Chinese Ceramic Society | 2022, 50(9) : 2388 - 2396
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Journal of the Chinese Ceramic Society | 2022, 50(9): 2388-2396
• Research Articles •
Preparation of Superhydrophilic-Superoleophobic Diatomite Porous Ceramics and Its Oil-Water Emulsion Continuous Separation Performance
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Lei HAN, Xiaojian LI, Faliang LI, Haijun ZHANG
Affiliations
  • The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
  • HAN Lei (1987-), male, Ph.D.. E-mail:

About Author:

HAN Lei (1987-), male, Ph.D.. E-mail:

Published: 2022-09-20 doi: 10.14062/j.issn.0454-5648.20220177
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Diatomite porous ceramics prepared by a foam-gelcasting route were used as a matrix, and SiO2 microspheres in-situ formed by a solvothermal method were used to modify the surface roughness of diatomite porous ceramics. Capstone FS-50 (CS-50) was used as a modifier to prepare SiO2 microspheres and CS-50 co-modified superhydrophilic-superoleophobic diatomite porous ceramics (SSMDPC) for the use of continuous separation of oil/water emulsions. The effects of TEOS/NH3·H2O addition and CS-50 concentration on the microstructure and wettability of the obtained samples as well as the oil/water separation continuous performance and extreme environmental stability were investigated. The results show that the maximum oil contact angles in air and water of the prepared SSMDPC are 153° and 158° respectively at TEOS/NH3·H2O addition of 5%/2% and CS-50 addition of 5% respectively. The continuous separation flux and separation efficiency of SSMDPC for edible oil/water mixture and edible oil-in-water emulsion with a surfactant (5/95, mass ratio) are 162.3 kg·min-1·m-2 and 98.3%, 93.7 kg·min-1·m-2 and 91.3%, respectively. Moreover, SMDPC can still maintain stable hydrophilic and hydrophobic properties under corrosion conditions (i.e., pH value of 1, pH value of 14 and 1 M NaCl), even at -196 ℃ and 200 ℃, which has broad application prospects in oil-in-water emulsion.

oil-water emulsion  /  superhydrophilic-superoleophobic  /  diatomite porous ceramics  /  surface modification
韩磊, 李孝建, 李发亮, 张海军. 超亲水-超疏油硅藻土多孔陶瓷制备及其连续油水乳液分离性能. 硅酸盐学报, 2022 , 50 (9) : 2388 -2396 . DOI: 10.14062/j.issn.0454-5648.20220177
Lei HAN, Xiaojian LI, Faliang LI, Haijun ZHANG. Preparation of Superhydrophilic-Superoleophobic Diatomite Porous Ceramics and Its Oil-Water Emulsion Continuous Separation Performance[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (9) : 2388 -2396 . DOI: 10.14062/j.issn.0454-5648.20220177
Year 2022 volume 50 Issue 9
25
2
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Article Info
doi: 10.14062/j.issn.0454-5648.20220177
  • Receive Date:2022-03-08
  • Online Date:2026-10-20
  • Published:2022-09-20
Article Data
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History
  • Received:2022-03-08
  • Revised:2022-03-22
Funding
Affiliations
    The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China

Corresponding:

ZHANG Haijun (1970-), male, Ph.D., Professor. E-mail:
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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