ZHANG Dianping (1981-), male, Doctoral candidate. E-mail: zhangdp@nxu.edu.cn
Silicon anode materials pulverization and deciduation from the collector can lead to the battery capacity fast attenuation and low conductivity due to the volume expansion of silicon during the lithiation/delithiation process. We prepared a kind of non-woven flexible silicon-based anode by an in-situ electrospinning method with nanosilicon self-controlled, and investigated the morphology, structure and electrochemical performance. The results show that the prepared non-woven silicon-based anode has a superior flexibility, and carbon after polyvinyl pyrrolidone cracking mainly exists in the form of amorphous carbon. The Si/C composite silicon-based anode fiber film has a high specific surface area and a structure with massive mesopores, and the first-cycle discharge capacity can reach 2 086.7 mA·h/g at a charge-discharge current density of 0.1 A/g, the initial Coulomb efficiency is 81.1%, and the discharge capacity can still maintain > 500 mA·h/g after 100 cycles.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |