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Progress and Prospect of Energy Storage of Metal Phosphide-Rich
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Wen CHEN1, Keyan HU1, Wujie DONG2, Fuqiang HUANG1, 2
Journal of the Chinese Ceramic Society | 2023, 51(6) : 1626 - 1639
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Journal of the Chinese Ceramic Society | 2023, 51(6): 1626-1639
• Review •
Progress and Prospect of Energy Storage of Metal Phosphide-Rich
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Wen CHEN1, Keyan HU1, Wujie DONG2, Fuqiang HUANG1, 2
Affiliations
  • 1.School of Mechanical and Electrical Engineering, Jingdezhen Ceramic University, Jingdezhen 333403, Jiangxi, China
  • 2.State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

    • CHEN Wen (1999-), female, Master Candidate. E-mail:

About Author:

CHEN Wen (1999-), female, Master Candidate. E-mail:

Published: 2023-06-20 doi: 10.14062/j.issn.0454-5648.20221084
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Phosphorus-based anode materials have a high theoretical capacity and a medium redox potential, and the related raw materials have some advantages in reserves and costs, thus having promising application prospects in sodium and lithium-ion battery anode materials. However, red phosphorus has a fast decay rate of electrochemical activity and a poor cycling performance due to the extremely low electronic conductivity and excessive volume expansion, while black phosphorus conductivity can reach 105 S/m, and its dense structure leads to a poor intrinsic rate performance, thus restricting the practical application of elemental phosphorus as an anode material. A unique metal phosphorus-rich phosphides MPx (x≥2) can be formed by introducing a small amount of metal elements into elemental phosphorus. The electronic conductivity of metal phosphorus-rich phosphides MPx can be greatly improved via metal element electron injection, and a relatively empty crystal structure can be formed to provide faster reaction kinetics and effectively inhibit volume expansion. Therefore, metal phosphorus-rich phosphides MPx with a high capacity and superior electron/ion transport characteristics is a potential sodium and lithium-ion battery anode material. This review mainly represented the composition and structural characteristics of metal phosphorus-rich phosphides, focusing on the latest progress in the energy storage mechanism and modification strategy of metal phosphorus-rich phosphides.

metal phosphorus-rich phosphides  /  anode materials  /  lithium ion batteries  /  sodium ion batteries
陈文, 胡克艳, 董武杰, 黄富强. 金属富磷化物储能研究进展与展望. 硅酸盐学报, 2023 , 51 (6) : 1626 -1639 . DOI: 10.14062/j.issn.0454-5648.20221084
Wen CHEN, Keyan HU, Wujie DONG, Fuqiang HUANG. Progress and Prospect of Energy Storage of Metal Phosphide-Rich[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (6) : 1626 -1639 . DOI: 10.14062/j.issn.0454-5648.20221084
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Year 2023 volume 51 Issue 6
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Article Info
doi: 10.14062/j.issn.0454-5648.20221084
  • Receive Date：2022-12-17
  • Online Date：2026-10-20
  • Published：2023-06-20
Article Data
Affiliations
History
  • Received：2022-12-17
  • Revised：2023-01-10
Funding
Affiliations
    1.School of Mechanical and Electrical Engineering, Jingdezhen Ceramic University, Jingdezhen 333403, Jiangxi, China
    2.State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

Corresponding:

DONG Wujie(1991-), male, Ph.D., Assistant Research Fellow. E-mail:
HUANG Fuqiang (1968-), male, Ph.D., Professor.
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表12种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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