YIN Xiangbin (1998-), male, Master candidate. E-mail: 1057985820@qq.com
To eradicate antibiotics from aqueous solution, cerium(Ce) doped ZnFe2O4 microspheres with different Ce mass ratios were prepared by a hydrothermal method and applied for the photocatalytic decomposition of tetracycline antibiotic. The results reveal that the introduction of Ce improves the charge separation for the photogenerated electron-hole pairs, which can be confirmed form the photocurrent spectra. The optimized sample ZnFe1.96Ce0.04O4 shows a decomposition rate of 56.6% under simulated solar light within 40 min. The trapping experiments show that hydroxyl radical and superoxide radical are the main degrading species, directly involving in the decomposition of antibiotics. Moreover, the rate of hydrogen produced from water splitting photocatalyzed by ZnFe1.96Ce0.04O4 reaches 230.4 μmol/(g·h) under simulated solar light irradiation.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |