ZHENG Jingjing (1981-), female, Ph.D., Associate Professor. E-mail: zjj65050@163.com
Photofenton technology is one of the effective means to treat organic wastewater. Developing photofenton catalysts with a higher catalytic efficiency is always a hotspot. A BiOI/MIL-100(Fe) nanocomposite with a visible-light response was synthesized by a facile hydrothermal-co-precipitation method. The as-synthesized BiOI/MIL-100(Fe) nanocomposite was characterized by X-ray diffraction, scanning electron microscopy, high resolution transmission electron microscopy, UV-vis diffuse reflectance spectroscopy and N2 adsorption-desorption analysis, respectively. The BiOI/MIL-100(Fe) nanocomposite exhibits a better photo-Fenton activity rather than pure BiOI and MIL-100(Fe) for tetracycline degradation under visible-light irradiation. In particular, the composite (BiOI/MIL-100(Fe)-2) has the maximum efficiency when a content of MIL-100(Fe) is 5.2% (in mass fraction). The formation of BiOI/MIL-100(Fe) heterojunctions between BiOI and MIL-100(Fe) is beneficial to the transfer and separation of charge carriers. The photogenerated electrons accelerate Fe2+/Fe3+ cycle and create the reductive reaction of H2O2. The enhanced performance of BiOI/MIL-100(Fe) nanocomposite is ascribed to a synergic effect for photocatalysis and Fenton reaction.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |