LI Shengyuan (1992-), male, Doctoral candidate. E-mail: lsy728@mail.ustc.edu.cn
The limited capacity and long charging time of graphite-based anodes for lithium-ion batteries cannot meet ever-growing demands. Developing anodes with a high capacity and a fast charging ability becomes a hotspot of the present research. Herein, an N-doped porous hard carbon (N-HC) was prepared via dehydration reaction of sucrose and sulfuric acid and subsequent annealing in NH3/Ar. The diffusion coefficient of Li+ in N-HC reaches 9.0×10-8 cm2·s-1 due to the rich ultra-micropore structure (i.e., pore size <0.75 nm) and the large interlayer spacing (i.e., 0.39 nm) in N-HC. The capacity of N-HC remains 704.0 mA·h·g-1 or 269.2 mA·h·g-1 after 680 or 1 400 cycles at 0.27 C or 2.7 C (1 C=370 mA·g-1). The N-HC electrode can meet the requirement of fast charging lithium-ion battery, while the initial Coulomb efficiency needs to be improved.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |