LI Biaoyang (1998-), male, Master candidate. E-mail: l_521529@163.com
Aqueous zinc-ion batteries (ZIBs) are considered to be prospective candidates in energy storage devices because of their excellent safety, crustal abundance, low cost and environmental benignity. Whereas, the design of a satisfied cathode material with a large specific capacity, superior rate performance and long-cycle life is still a significant challenge for ZIBs. Herein, a new strategy is proposed to use W doped V2O5 as cathode material for aqueous ZIBs. The W doping can effectively enlarge the lattice spacing and ion migration efficiency of V2O5, and the formation of W—O bond can obviously alleviate the capacity decay problem caused by structural damage and low intrinsic conductivity in the cycling process. As a result, the V2O5-W cathode exhibits an excellent capacity of 195.0 mA·h/g after 100 cycles at 0.1 A/g, and an impressive rate capability of 243.0 mA·h/g at the high current density of 1 A/g after 1 000 cycles. This work provides a simple, efficient and feasible strategy for designing high-performance cathode materials in ZIBs.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |