HELIAN Yizhe (1995-), male, Ph.D. E-mail: helian@emails.bjut.edu.cn
The low denitration activity and stability of MnOx/TiO2 catalyst are still challenging. In this work, a MnOx/TiO2 catalyst was modified via a polarization effect with tourmaline. Tourmaline with a proper fineness can improve the denitration performance of the catalytic material, obtaining the greater denitration rate above 90% in a wide temperature range and the prolonged high-efficiency denitration time. Based on the results of in-situ Fourier transform infrared spectroscopy, the reaction mechanism of the catalysts before and after modification with tourmaline follows the Langmuir-Hinshelwood mechanism, and tourmaline polarization can accelerate the adsorption rate of reaction gas and generate intermediate products liable for subsequent reaction, thus improving the denitration performance.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |