ZHANG Wensheng (1969-), male, Ph.D., Professor. E-mail: wensheng_zhang01@163.com
High-magnesium Portland cement clinker with MgO content of 6% was synthesized with chemical reagent. The effect of cooling method (i.e., furnace cooling, air cooling and liquid-nitrogen quenching) on the mineral composition, C3S crystal type, solid solubility of MgO, and formation of periclase of high-magnesium Portland clinkers with different alumina modulus (IM) (i.e., 0.64, 1.10 and 3.00) was investigated. The samples were characterized by X-ray powder diffraction with Rietveld method, petrographic method and scanning electron microscopy. The results show that a rapid cooling can stabilize C3S crystal into M3 type, and prevent the transformation of C3S crystal from M3 to T3 type. And this has a little effect on the change of IM. The content of C3S is relatively high in the clinker with a low IM and by furnace cooling, and the clinker with a high IM and by liquid-nitrogen quenching. Rapid cooling rate inhibits the crystallization of periclase, and the inhibition effect is more dominant in a low IM clinker. Clinker quenching can keep the morphology of C3S intact, and promote periclase to turn into a fine round granule.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |