Home Journals Articles Updates About
CN
image
收藏切换
Formation Mechanism of Fullerenes and Metallofullerenes
收藏切换
Zihui HUA1, 2, Bo WU1, 2, Lihua GAN3, Hui LI4, 5, Chunru WANG1, 2
Journal of the Chinese Ceramic Society | 2023, 51(2) : 323 - 331
Less
收藏切换
Journal of the Chinese Ceramic Society | 2023, 51(2): 323-331
• Review •
Formation Mechanism of Fullerenes and Metallofullerenes
Full
Zihui HUA1, 2, Bo WU1, 2, Lihua GAN3, Hui LI4, 5, Chunru WANG1, 2
Affiliations
  • 1.Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • 2.School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
  • 3.School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China
  • 4.Beijing Fullcan Biotechnology Co. Ltd, Beijing 100085, China
  • 5.Chifeng Fullcan Biotechnology Co., Ltd, Chifeng 024000, Inner Mongolia, China

    • HUA Zihui (1997-), male, Master candidate. E-mail:

About Author:

HUA Zihui (1997-), male, Master candidate. E-mail:

Published: 2023-02-20 doi: 10.14062/j.issn.0454-5648.20220517
Outline
收藏切换

Fullerenes and metallofullerenes have unique structure and novel electronic characteristics, which have great application potential in biomedicine, quantum and information fields. However, how to increase the yields of metallofullerenes is a key technical problem that must be solved for practical application. In order to synthesize metallofullerenes with high yields and selectivity, it is necessary to understand the formation mechanism and develop new synthesis methods. Our research focuses on the comprehensive analysis of the formation mechanism of fullerenes and metallofullerenes in order to find a way to break through the bottleneck of their productivity. On the one hand, the formation process of fullerenes was simulated by density functional theory and molecular dynamics, which directed the optimization of the synthesis conditions of fullerenes. On the other hand, a series of metallofullerenes with specific structures and functions were prepared by accurately controlling the inert gas pressure, arc gas composition and raw material composition of metallofullerenes, and the efficient preparation strategy of metallofullerenes was developed. Finally, we also explored the protection methods after the formation of metallofullerenes, and achieved certain results, laying a solid foundation for the industrialization of metallofullerenes in the future.

fullerenes  /  metallofullerenes  /  formation mechanism  /  density functional theory  /  molecular dynamics simulation
华紫辉, 吴波, 甘利华, 李慧, 王春儒. 富勒烯及金属富勒烯的形成机理. 硅酸盐学报, 2023 , 51 (2) : 323 -331 . DOI: 10.14062/j.issn.0454-5648.20220517
Zihui HUA, Bo WU, Lihua GAN, Hui LI, Chunru WANG. Formation Mechanism of Fullerenes and Metallofullerenes[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (2) : 323 -331 . DOI: 10.14062/j.issn.0454-5648.20220517
Appendix
Less
Year 2023 volume 51 Issue 2
31
5
Cite this Article
BibTeX
Article Info
doi: 10.14062/j.issn.0454-5648.20220517
  • Receive Date：2022-06-27
  • Online Date：2026-10-20
  • Published：2023-02-20
Article Data
Affiliations
History
  • Received：2022-06-27
  • Revised：2022-07-18
Funding
Affiliations
    1.Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
    2.School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
    3.School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China
    4.Beijing Fullcan Biotechnology Co. Ltd, Beijing 100085, China
    5.Chifeng Fullcan Biotechnology Co., Ltd, Chifeng 024000, Inner Mongolia, China

Corresponding:

WU Bo (1988-), female, Ph.D., Associate Professor; E-mail:
WANG Chunru (1965-), male, Ph.D., Professor.
References
Share
https://castjournals.cast.org.cn/joweb/gsyxb/EN/10.14062/j.issn.0454-5648.20220517
Share to
QR

Scan QR to access full text

Cite this article
BibTeX
Citations
表12种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
关闭全屏
  • BibTeX
  • EndNote
  • RefWorks
  • TxT
Links
Articles
Latest Articles
Most Read
Collections
Updates
Events
News
Multimedia
About
About Us
Contact
No. 86 Xueyuan South Road, Haidian District, Beijing
100081
010-62662699(Operation and Technical Support)
qkjq@cast.org.cn

Copyright © 2025 China Association for Science and Technology. All rights reserved. For all open access content, the relevant licensing terms apply.
Sponsored by the Office of the Leading Group for Cybersecurity and Informatization of CAST, and supported by Science and Technology Review Publishing House