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Optical Thermometry Based on Fluorescence Intensity Ratio in Dual-Phases Glass Ceramics Containing LiYF4∶Ln3+(Ln=Tb, Dy) and ZnAl2O4∶Cr3+ Nanocrystals
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Xinyue LI1, Yuzheng TONG1, Jidong LIN2, Shaoxiong WANG2, Shichen LI3, Daqin CHEN1
Journal of the Chinese Ceramic Society | 2022, 50(4) : 966 - 974
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Journal of the Chinese Ceramic Society | 2022, 50(4): 966-974
• Research Articles •
Optical Thermometry Based on Fluorescence Intensity Ratio in Dual-Phases Glass Ceramics Containing LiYF4∶Ln3+(Ln=Tb, Dy) and ZnAl2O4∶Cr3+ Nanocrystals
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Xinyue LI1, Yuzheng TONG1, Jidong LIN2, Shaoxiong WANG2, Shichen LI3, Daqin CHEN1
Affiliations
  • 1.College of Materials & Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, China
  • 2.College of Physics and Energy, Fujian Normal University, Fuzhou 350117, China
  • 3.School of Materials Science and Engineering, Central South University, Changsha 410083, China
  • LI Xinyue (1990-), female, Ph. D., associate Professor. E-mail:

About Author:

LI Xinyue (1990-), female, Ph. D., associate Professor. E-mail:

Published: 2022-04-20 doi: 10.14062/j.issn.0454-5648.20211030
Outline
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Dual-phases glass ceramics (GCs) containing LiYF4∶Ln3+(Ln=Eu, Tb, Dy) and ZnAl2O4∶Cr3+ nanocrystals (NCs) were fabricated by a conventional melt-quenching method. The structural and spectrographic characterizations indicate that Ln3+ can be doped into LiYF4 lattice and Cr3+ can be introduced into ZnAl2O4 lattice, respectively. In this regard, the luminescent centers are physically separated through a spatial isolation strategy, getting rid of adverse energy transfer processes. The dual-modal luminescence of Ln3+ and Cr3+ can be thus attained simultaneously. Also, optical thermometry based on the fluorescence intensity ratio (FIR) of Ln3+/Cr3+ is performed. Under irradiation upon 377 nm, the FIR value for Tb3+∶5D4→7F5 and Cr3+∶2E→4A2 transitions varies acutely, with a maximal relative sensitivity of 0.80%·K-1 at 570 K. The FIR-based optical thermometry for Dy3+∶4F9/2→6H13/2 and Cr3+∶2E→4A2 transitions is carried out, with a maximal relative sensitivity of 0.86%·K-1 at 573 K. As a consequence, the dual-phases GCs can be an ideal medium for the spatial isolation of luminescent centers, suppressing an adverse energy transfer process and realizing an efficient dual-mode luminescence. This is beneficial to the application of FIR-based optical thermometry for GC materials.

dual-phases glass ceramics  /  fluorescence intensity ratio  /  optical thermometry  /  nanocrystal
李心悦, 童宇正, 林继栋, 王少雄, 李世晨, 陈大钦. 基于LiYF4∶Ln3+(Ln=Tb, Dy)和ZnAl2O4∶Cr3+双晶相玻璃陶瓷的荧光强度比温度传感特性. 硅酸盐学报, 2022 , 50 (4) : 966 -974 . DOI: 10.14062/j.issn.0454-5648.20211030
Xinyue LI, Yuzheng TONG, Jidong LIN, Shaoxiong WANG, Shichen LI, Daqin CHEN. Optical Thermometry Based on Fluorescence Intensity Ratio in Dual-Phases Glass Ceramics Containing LiYF4∶Ln3+(Ln=Tb, Dy) and ZnAl2O4∶Cr3+ Nanocrystals[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (4) : 966 -974 . DOI: 10.14062/j.issn.0454-5648.20211030
Year 2022 volume 50 Issue 4
15
4
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Article Info
doi: 10.14062/j.issn.0454-5648.20211030
  • Receive Date:2021-11-30
  • Online Date:2026-10-22
  • Published:2022-04-20
Article Data
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History
  • Received:2021-11-30
  • Revised:2021-12-20
Funding
Affiliations
    1.College of Materials & Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, China
    2.College of Physics and Energy, Fujian Normal University, Fuzhou 350117, China
    3.School of Materials Science and Engineering, Central South University, Changsha 410083, China

Corresponding:

LI Shichen(1975-), male, Master, Senior Engineer; E-mail:
CHEN Daqin (1978-), male, Ph.D., Professor.
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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