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Alkali Vapor Attack Behavior of Al2O3-SiO2 Refractory Raw Materials
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Zhifeng WANG1, Yawei LI1, Yibiao XU1, Shaobai SANG1, Shulong MA2, Haibo ZHANG2, Changhe GAO2
Journal of the Chinese Ceramic Society | 2022, 50(6) : 1694 - 1700
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Journal of the Chinese Ceramic Society | 2022, 50(6): 1694-1700
• Research Articles •
Alkali Vapor Attack Behavior of Al2O3-SiO2 Refractory Raw Materials
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Zhifeng WANG1, Yawei LI1, Yibiao XU1, Shaobai SANG1, Shulong MA2, Haibo ZHANG2, Changhe GAO2
Affiliations
  • 1.The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
  • 2.Beijing Jinyu Tongda Refractory Technologies Ltd., Beijing 100085, China
  • WANG Zhifeng (1982-), male, Doctorial candidate. E-mail:

About Author:

WANG Zhifeng (1982-), male, Doctorial candidate. E-mail:

Published: 2022-06-20 doi: 10.14062/j.issn.0454-5648.20210949
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Sewage sludge and household garbage are used as an alternative fuel in recent production of cement. However, the alternative fuel causes serious alkali attack and spalling of bauxite-SiC refractories for cement kiln lining, thus having an impact on the operation of the cement kiln. In this paper, the alkali vapor exposure was used to evaluate alkali attack on some raw materials like bauxite, mullite (M60) and molochite, which were used to prepare mullite-SiC composite refractory as a lining of cement kiln. The results show that the alkali attack resistance of these raw materials is closely related to their chemical composition, phase composition and microstructures. Bauxite with corundum and mullite as main phases is attacked by alkali to form a kaliophilite phase and induce cracks and loose structure, further enhancing gaseous alkali penetration and serious damage. Mullite (M60) with mullite as a main phase is attacked by alkali to form leucite and transient liquid phase. The resultant liquid phase prevents from the penetration of alkali, and the attack only occurs on the surface layer, so mullite (M60) exhibits a superior alkali attack resistance. Molochite with mullite and glass (the content of 46%) reacts with alkali vapor to form more liquid phase and leucite. As alkali vapor is dissolved in the glass phase of molochilte, the integrity of molochite is destroyed by alkali attack.

alumina-silica refractory raw materials  /  alumina  /  silica  /  alkali vapor  /  alkali attack behavior
王治峰, 李亚伟, 徐义彪, 桑绍柏, 马淑龙, 张海波, 高长贺. 铝硅系耐火原料与碱蒸气反应侵蚀行为. 硅酸盐学报, 2022 , 50 (6) : 1694 -1700 . DOI: 10.14062/j.issn.0454-5648.20210949
Zhifeng WANG, Yawei LI, Yibiao XU, Shaobai SANG, Shulong MA, Haibo ZHANG, Changhe GAO. Alkali Vapor Attack Behavior of Al2O3-SiO2 Refractory Raw Materials[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (6) : 1694 -1700 . DOI: 10.14062/j.issn.0454-5648.20210949
Year 2022 volume 50 Issue 6
16
2
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Article Info
doi: 10.14062/j.issn.0454-5648.20210949
  • Receive Date:2021-11-05
  • Online Date:2026-10-22
  • Published:2022-06-20
Article Data
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History
  • Received:2021-11-05
  • Revised:2022-01-20
Funding
Affiliations
    1.The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
    2.Beijing Jinyu Tongda Refractory Technologies Ltd., Beijing 100085, China

Corresponding:

LI Yawei (1966-), male, Ph. D., Professor. E-mail:
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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