ZHAO Yanzhao(1964-), male, Ph.D., Professor. E-mail: zhaoy@sust.edu.cn
According to MgO-A12O3-SiO2 ternary system phase diagram, 22 kinds of compositions were designed by using triangular rule, and cordierite was synthesized by melting sintering method. The crystal evolution and phase transition of cordierite glass-ceramics was studied by means of differential thermal analysis, X-ray diffraction and scanning electron microscope. The apparent porosity and thermal expansion properties were tested. The results show that there are two kinds of exothermic peaks in the differential thermal curve with the change of composition. Near the theoretical composition, a double crystallization exothermic peak occurs, and MgAl2Si3O10 and α-cordierite crystal phase is precipitated. The thermal expansion coefficient of cordierite under the theoretical composition is the lowest, which is 1.27×10-6/℃. However, when the MgO content in the composition increases to more than 16.6%, the exothermic peak of crystallization is unimodal, and only α-cordierite crystal phase is precipitated under the single peak. At this time, the apparent porosity of cordierite sample is on the decrease significantly, with a minimum value of 0.32%.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |