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Effect of Charge Compensator Mg2+ on Luminescent Properties of CaAl12(PO4)0.1O18.85:Mn4+ Red Phosphor
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Han ZHANG1, 2, Guodong FAN1, 2, Fangyi RUAN1, 2, Qianhong PAN3
Journal of the Chinese Ceramic Society | 2021, 49(9) : 1985 - 1993
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Journal of the Chinese Ceramic Society | 2021, 49(9): 1985-1993
• Research Article •
Effect of Charge Compensator Mg2+ on Luminescent Properties of CaAl12(PO4)0.1O18.85:Mn4+ Red Phosphor
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Han ZHANG1, 2, Guodong FAN1, 2, Fangyi RUAN1, 2, Qianhong PAN3
Affiliations
  • 1.College of Chemistry and Chemical Engineering, Shaanxi University of Science &Technology, Xi'an 710021, China
  • 2.Key Laboratory of Auxiliary Chemistry & Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science & Technology, Xi'an 710021, China
  • 3.Xi'an Changqing Chemical Group Co., LTD, Xi'an 710018, China

    • ZHANG Han (1995-), female, Master candidate. E-mail:

About Author:

ZHANG Han (1995-), female, Master candidate. E-mail:

Published: 2021-09-20 doi: 10.14062/j.issn.0454-5648.20210014
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A novel red-emitting phosphor CaAl12-x-y(PO4)0.1O18.85: xMn4+, yMg2+ was synthesized by a high-temperature solid-state method. The crystal structure and luminescence properties of the samples were characterized by X-ray diffraction, scanning electron microscopy and fluorescence spectroscopy. The results show that the synthesized phosphor has a hexagonal crystal structure with the space group of P63/mmc. The optimal doping amounts of Mn4+ and Mg2+ are x of 0.01 and y of 0.1, respectively. Under excitation at 396 nm, CaAl11.89(PO4)0.1O18.85: 0.01Mn4+, 0.1Mg2+ phosphor shows the maximum red light emission at 654 nm, corresponding to 2E→4A2g transition of Mn4+. The luminescence intensity and lifetime of phosphor are improved due to the co-doping with Mg2+ charge compensator. The absolute quantum efficiency of phosphor is 60%, the fluorescence lifetime is 0.97 ms, the color coordinate is in the deep-red region, and the color purity is 97%. The luminescence intensity is still 60% of the initial intensity when the temperature increases to 413K, indicating that this red phosphor with a superior thermal stability is a novel red luminescent material with broad application prospects.

manganese ion  /  charge compensation  /  aluminum phosphate  /  red-emitting phosphor  /  white-light-emitting diodes
张晗, 樊国栋, 阮方毅, 潘谦宏. 电荷补偿剂Mg2+对CaAl12(PO4)0.1O18.85：Mn4+红色荧光粉发光性能的影响. 硅酸盐学报, 2021 , 49 (9) : 1985 -1993 . DOI: 10.14062/j.issn.0454-5648.20210014
Han ZHANG, Guodong FAN, Fangyi RUAN, Qianhong PAN. Effect of Charge Compensator Mg2+ on Luminescent Properties of CaAl12(PO4)0.1O18.85:Mn4+ Red Phosphor[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (9) : 1985 -1993 . DOI: 10.14062/j.issn.0454-5648.20210014
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Year 2021 volume 49 Issue 9
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Article Info
doi: 10.14062/j.issn.0454-5648.20210014
  • Receive Date：2021-01-06
  • Online Date：2026-10-30
  • Published：2021-09-20
Article Data
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History
  • Received：2021-01-06
  • Revised：2021-04-20
Funding
Affiliations
    1.College of Chemistry and Chemical Engineering, Shaanxi University of Science &Technology, Xi'an 710021, China
    2.Key Laboratory of Auxiliary Chemistry & Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science & Technology, Xi'an 710021, China
    3.Xi'an Changqing Chemical Group Co., LTD, Xi'an 710018, China

Corresponding:

FAN Guodong (1964-), male, Ph.D., Professor. E-mail:
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表12种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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