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Luminous Properties of Tb3+/Ce3+ Doped Aluminosilicate Luminescent Glass Prepared with High Aluminum Blast Furnace Slag
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Kailong QIN1, Fabin CAO1, 2, Linling ZHU2, Weiming LIU1, 2, Xingmei SHEN1, Xingrong WU2, Zhaojin WU2
Journal of the Chinese Ceramic Society | 2021, 49(4) : 757 - 762
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Journal of the Chinese Ceramic Society | 2021, 49(4): 757-762
Luminous Properties of Tb3+/Ce3+ Doped Aluminosilicate Luminescent Glass Prepared with High Aluminum Blast Furnace Slag
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Kailong QIN1, Fabin CAO1, 2, Linling ZHU2, Weiming LIU1, 2, Xingmei SHEN1, Xingrong WU2, Zhaojin WU2
Affiliations
  • 1.Key Laboratory of Metallurgical Emission Reduction & Resources Recycling (Anhui University of Technology), Minstry of Education, Maanshan 243002, Anhui, China
  • 2.Anhui Province Key Laboratory of Metallurgical Engineering & Resources Recycling, Maanshan 243002, Anhui, China

    • QIN Kailong (1992-), male, Master candidate. E-mail:

About Author:

QIN Kailong (1992-), male, Master candidate. E-mail:

Published: 2021-04-20 doi: 10.14062/j.issn.0454-5648.20200546
Outline
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Tb3+ single doped and Tb3+/Ce3+ co-doped high aluminum blast furnace slag, aluminosilicate luminescent glass was prepared by a high-temperature water-quenching method. The effects of heat treatment and co-doping on the luminous properties of glass were studied. The results show that, after holding at 1 000℃ for 4 h, the glass host crystallizes into Ca2(Mg0.5Al0.5)(Si1.5Al0.5O7), and the luminescence performance drops sharply. The highest luminous intensity of 4%(mole fraction) Tb3+ doped luminous glass is about 12 times higher than of that crystallized. With Ce3+ ions introduced, energy transfer occurs between Ce3+ ions and Tb3+ ions due to multipolar interaction, and the luminous intensity of Tb3+/Ce3+ co-doped luminescent glass reaches nearly 6 times of the Tb3+ single doped. 4%Tb3+/1%Ce3+ co-doped luminescent glass has good luminescence thermal stability at 150℃, and can be used as a green solid-state luminescent material excited by near ultraviolet LED.

high aluminum blast furnace slag  /  luminescent glass  /  energy transfer  /  luminescence thermal stability
秦凯龙, 曹发斌, 朱霖玲, 刘伟明, 申星梅, 武杏荣, 吴照金. Tb3+/Ce3+掺杂高铝高炉渣构筑硅铝酸盐发光玻璃的发光性能. 硅酸盐学报, 2021 , 49 (4) : 757 -762 . DOI: 10.14062/j.issn.0454-5648.20200546
Kailong QIN, Fabin CAO, Linling ZHU, Weiming LIU, Xingmei SHEN, Xingrong WU, Zhaojin WU. Luminous Properties of Tb3+/Ce3+ Doped Aluminosilicate Luminescent Glass Prepared with High Aluminum Blast Furnace Slag[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (4) : 757 -762 . DOI: 10.14062/j.issn.0454-5648.20200546
Appendix
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Year 2021 volume 49 Issue 4
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Article Info
doi: 10.14062/j.issn.0454-5648.20200546
  • Receive Date：2020-07-23
  • Online Date：2026-10-30
  • Published：2021-04-20
Article Data
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History
  • Received：2020-07-23
  • Revised：2020-08-11
Funding
Affiliations
    1.Key Laboratory of Metallurgical Emission Reduction & Resources Recycling (Anhui University of Technology), Minstry of Education, Maanshan 243002, Anhui, China
    2.Anhui Province Key Laboratory of Metallurgical Engineering & Resources Recycling, Maanshan 243002, Anhui, China

Corresponding:

CAO Fabin (1973-), male, Ph.D., Associate Professor. E-mail:
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表12种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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