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Softening Characteristics and Verification of Al2O3-SiO2-CaO Based Sealing Materials for Large-Scale Anode-Supported Planar Solid Oxide Fuel Cell Stacks
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Jingjing LU1, Fuxing MIAO1, Haisen REN2, Wanbing GUAN3
Journal of the Chinese Ceramic Society | 2021, 49(1) : 20 - 25
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Journal of the Chinese Ceramic Society | 2021, 49(1): 20-25
• Special Issue on SOFC •
Softening Characteristics and Verification of Al2O3-SiO2-CaO Based Sealing Materials for Large-Scale Anode-Supported Planar Solid Oxide Fuel Cell Stacks
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Jingjing LU1, Fuxing MIAO1, Haisen REN2, Wanbing GUAN3
Affiliations
  • 1.Key Laboratory of Impact and Safety Engineering (Ningbo University), Ministry of Education, Ningbo 315211, Zhejiang, China
  • 2.Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
  • 3.Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, Zhejiang, China
  • LU Jingjing (1997-), male, Undergraduate. E-mail:

About Author:

LU Jingjing (1997-), male, Undergraduate. E-mail:

Published: 2021-01-20 doi: 10.14062/j.issn.0454-5648.20200260
Outline
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Al2O3-SiO2-CaO-based sealing material was developed. The properties of high-temperature crystallization/softening, thermal behavior and interfacial bonding of the sealing material were observed in situ. The results show that the sealing material begins to soften at 850℃, spheroidizes at 900-1 000℃ and keeps amorphous at <1 100℃. In addition, the sealing material has a slight mass loss according to the thermal analysis, and it is bonded with the interconnect and the cell tightly, which is conducive to the application in solid oxide fuel cell (SOFC) stack. Two 5-cell solid oxide fuel cell (SOFC) stacks were assembled by the sealing material. The cycling and stability performance of SOFC stacks were tested. The results indicate that the open circuit voltage (OCV) of the stack reaches 6.0 V, showing an average OCV of 1.2 V for single cells. The stack 1 is operated under cycling conditions, showing no degradation before and after cycling. The stack 2 is operated under stability conditions, exhibiting no degradation for 300 h operation.

sealed glass  /  softening temperature  /  spheroidizing temperature  /  stack  /  solid oxide fuel cell
卢晶晶, 缪馥星, 任海森, 官万兵. 应用于大尺寸平板型固体燃料电池电堆的Al2O3-SiO2-CaO基密封材料软化特性及其验证. 硅酸盐学报, 2021 , 49 (1) : 20 -25 . DOI: 10.14062/j.issn.0454-5648.20200260
Jingjing LU, Fuxing MIAO, Haisen REN, Wanbing GUAN. Softening Characteristics and Verification of Al2O3-SiO2-CaO Based Sealing Materials for Large-Scale Anode-Supported Planar Solid Oxide Fuel Cell Stacks[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (1) : 20 -25 . DOI: 10.14062/j.issn.0454-5648.20200260
Year 2021 volume 49 Issue 1
28
12
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Article Info
doi: 10.14062/j.issn.0454-5648.20200260
  • Receive Date:2020-04-10
  • Online Date:2026-10-30
  • Published:2021-01-20
Article Data
Affiliations
History
  • Received:2020-04-10
  • Revised:2020-05-24
Funding
Affiliations
    1.Key Laboratory of Impact and Safety Engineering (Ningbo University), Ministry of Education, Ningbo 315211, Zhejiang, China
    2.Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
    3.Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, Zhejiang, China

Corresponding:

MIAO Fuxing (1980-), female, Associate Professor; E-mail:
GUAN Wanbing (1980-), male, Professor.
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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