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Surface Modification of TiO2 Nanosheet Array and Its Application in Hybrid Solar Cells
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Xue ZHAO, Juan PEI, Xueting HUANG, Yanzhong HAO
Journal of the Chinese Ceramic Society | 2020, 48(10) : 1559 - 1566
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Journal of the Chinese Ceramic Society | 2020, 48(10): 1559-1566
Surface Modification of TiO2 Nanosheet Array and Its Application in Hybrid Solar Cells
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Xue ZHAO, Juan PEI, Xueting HUANG, Yanzhong HAO
Affiliations
  • College of Sciences, Hebei University of Science and Technology, Shijiazhuang 050018, China

    • ZHAO Xue (1995-), female, Master candidate. E-mail:

About Author:

ZHAO Xue (1995-), female, Master candidate. E-mail:

Published: 2020-10-20 doi: 10.14062/j.issn.0454-5648.20200007
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TiO2 nanosheets (TNS) were prepared on fluorine-doped tin oxide (FTO) glass via hydrothermal reaction, and triphenylamine complex D2 was used to modify the TNS array. The microstructure and photoelectric conversion performance of hybrid solar cells were characterized by scanning electronic microscopy, X-ray diffraction, ultraviolet-visible spectroscopy, transient photocurrent spectroscopy, photoluminnescence spectroscopy, contact angle measurement, current density-voltage (J-V) test, and electrochemical impedance spectroscopy. The results show that triphenylamine complex D2 improves the chemical compatibility between organic polymers and inorganic materials. According to the results by contact angle measurement, the surface of TiO2 particles changes from hydrophilic to hydrophobic after modification. The results by electrochemical impedance spectroscopy indicate that the recombination resistance and electronic lifetime of the cell device after modified on the surface of TiO2 particles increase from 866.8 Ω·cm2 and 48.1 μs to 932.2 Ω·cm2 and 127.1 μs, respectively. In the TNS-based hybrid solar cell, the photoelectric conversion efficiency of the modified cell improves from 0.20% to 1.52%, compared to that of the unmodified device.

titanium dioxide nanosheets  /  surface modification  /  hybrid solar cell  /  photoelectric conversion efficiency
赵雪, 裴娟, 黄雪婷, 郝彦忠. TiO2纳米片阵列的表面改性及其在杂化太阳能电池中的应用. 硅酸盐学报, 2020 , 48 (10) : 1559 -1566 . DOI: 10.14062/j.issn.0454-5648.20200007
Xue ZHAO, Juan PEI, Xueting HUANG, Yanzhong HAO. Surface Modification of TiO2 Nanosheet Array and Its Application in Hybrid Solar Cells[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (10) : 1559 -1566 . DOI: 10.14062/j.issn.0454-5648.20200007
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Year 2020 volume 48 Issue 10
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Article Info
doi: 10.14062/j.issn.0454-5648.20200007
  • Receive Date：2020-01-06
  • Online Date：2026-10-29
  • Published：2020-10-20
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History
  • Received：2020-01-06
  • Revised：2020-03-24
Funding
Affiliations
    College of Sciences, Hebei University of Science and Technology, Shijiazhuang 050018, China

Corresponding:

PEI Juan (1981-), female, Ph.D., Professor. E-mail:
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表12种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
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Genus		 种数
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Percentage of total
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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