HU Na (1984−), female, Ph.D., Senior Experimentalist. E-mail: huna@jxnu.edu.cn
Zeolite L with a Si/Al moles ratio of 1.9 was synthesized from initial concentrated gel in the absence of organic templates. The crystallization behavior and the crystal microstructure during crystallization were analyzed by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, nitrogen adsorption-desorption and energy dispersive X-ray spectroscopy. The effects of synthesis parameters such as synthesis time, aging time and molar compositions on the crystal growth were investigated. The results show that as-synthesized zeolite nanocrystals possess hierarchical structure. Pure zeolite L with a high crystallinity was obtained within a wide ratio range of gel SiO2/Al2O3 of 20-100. Moreover, the adsorption performance of the samples under the optimized synthesis conditions were evaluated via the equilibrium adsorption of pure gases CO2, CH4 and N2 at 25 ℃. Zeolite nanocrystals exhibit a high CO2 adsorption capacity.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |