Objective The Late Ordovician to Early Silurian represents a critical transition in Earth's history, characterized by the Hirnantian glaciation and the end-Ordovician mass extinction event. However, significant uncertainties persist in the chronostratigraphic framework for this interval, limiting our understanding of the mechanisms driving biotic extinction and climatic evolution. This study aims to establish a high-resolution absolute astronomical time scale for the Late Ordovician-Early Silurian through the integration of cyclostratigraphy and isotopic geochronology, providing robust temporal constraints for major geological events. Methods Three sections (Shuanghe in Chang-ning, Sichuan; Anwen in Qijiang, Chongqing; and Wangjiawan in Yichang, Hubei) were selected as study sites. High-resolution elemental data (Si, Fe, Ca, Al, Rb/Sr, etc.) were analyzed using AnalySeries and Acycle software to identify Milankovitch cycle signals. Sedimentation rates were estimated using the COCO/eCOCO and TimeOpt methods to construct floating astronomical time scales. CA-ID-TIMS zircon U-Pb dating was conducted on volcanic ash beds to obtain absolute age anchors, enabling precise conversion from the depth domain to the time domain. Results (1) Stable sedimentary cycles corresponding to 405-kyr and ~100-kyr long and short eccentricity cycles were identified in the XRF elemental series. Floating astronomical time scales of 12.2 Myr, 10.3 Myr, and 2.75 Myr were established for the Shuanghe section, Anwen section, and Wangjiawan section, respectively. (2) Given the most complete geological record preserved in the Shuanghe section, the ages of the Ordovician/Silurian (O/S) boundary and the base of the Hirnantian stage, calibrated to 442.34 ± 0.22 Ma and 443.78 ± 0.22 Ma respectively through cyclostratigraphic analysis combined with U-Pb dating of volcanic ash beds (Shuanghe section: 438.47 ± 0.17 Ma), can serve as a candidate for future international chronostratigraphic standards. (3) The duration of the Hirnantian stage is 1.44 Myr at the Shuanghe section, but only ~0.41 Myr at the Wangjiawan section, suggesting that a sedimentary hiatus may exist in the Wangjiawan section. (4) Paleoclimatic proxies and sea-level changes exhibited long-period fluctuations of 1.2 Myr and 2.4 Myr. Conclusions The high-precision astronomical time scale established in this study significantly improves the accuracy of the chronostratigraphic framework for the Late Ordovician-Early Silurian, revealing the rapid onset of the end-Ordovician mass extinction. Astronomical cycles played a significant role in driving climate-environmental evolution during this interval, providing key temporal constraints for understanding the triggering mechanisms of the end-Ordovician mass extinction.
Significance The study of the provenance of fine-grained sedimentary rocks is a crucial first step in the "source-to-sink" system theory of fine-grained sedimentary rocks. It is important for restoring the ancient sedimentary environment, understanding the formation mechanism of fine-grained sedimentary rocks, and predicting the distribution of unconventional oil and gas resources. Fine-grained sedimentary rocks are characterized by small particle size, complex composition, and difficulty in observation and research, with different material components corresponding to a variety of sources and origins. A review of the existing research results worldwide shows that currently there is a lack of systematic organization and summary of research outcomes regarding the provenance and origins of fine-grained sedimentary materials. Progress This paper synthesizes current research findings and categorizes the sources of fine-grained sedimentary rocks into three major types: terrigenous, endogenic, and volcanic-hydrothermal. It provides an in-depth summary and conclusion on the common sources and origins of fine-grained sediments, pointing out: (1) Clay minerals are of detrital weathering origin, diagenetic transformation from other minerals, transformation among clay minerals themselves, hydrolysis of submarine volcanic materials, and biologically mediated by extracellular polymeric substances; (2) Quartz mainly originates from the weathering of terrigenous materials, intra-basin biological activity, devitrification of volcanic ash materials, and authigenic formation; (3) Feldspar originates from the weathering of terrigenous detritus, input from volcanic-hydrothermal activity, and recent studies have also indicated that feldspar can be formed through microbial chemical processes; (4) Carbonate minerals are primarily endogenic, formed through chemical, bio-chemical, biological, and re-transport and deposition processes within the basin, and the input of terrigenous and volcanic-hydrothermal materials not only directly provides carbonate minerals for fine-grained sedimentary rocks but also promotes the formation of carbonate minerals within the basin; (5) Pyrite is mainly formed by the two ore-forming elements, iron and sulfur, through dissimilatory iron reduction and iron shuttling mechanisms, microbial reduction, and thermogenic reduction of sulfate within the basin; (6) Organic matter can be divided into terrigenous vitrinite, inertinite, and some liptinite, as well as endogenic liptinite, zooclastic organic debris, and secondary organic matter. [Conclusions and Perspectives] Future research on the provenance and origins of fine-grained sedimentary rocks will develop in a multidisciplinary and high-precision direction, and there is still an urgent need for a systematic approach suitable for the study of the provenance of fine-grained sedimentary rocks.This paper aims to clarify the provenance and origins of fine-grained sedimentary rocks, enhance the understanding of the sources and formation mechanisms of fine-grained sediments, and thus promote the development of fine-grained sedimentology theory. It provides a solid theoretical foundation and scientific basis for identifying the distribution characteristics of fine-grained sedimentary strata and predicting the distribution of unconventional oil and gas resources.
Significance Sepiolite is a clay mineral with a unique fibrous crystal structure; it has a significant potential application in the geological field due to its high adsorptive capacity and thermal stability. Progress The genesis types for sepiolite include direct deposition, terrestrial transport sedimentation and diagenetic alteration. Direct deposition is influenced by chemical conditions such as element concentration and pH. Terrestrial transport sedimentation is closely related to the geological environment and climatic conditions. Diagenetic alteration of sepiolite is affected by the burial depth and the properties of the hydrothermal fluids. Sepiolite is generally formed in an alkaline reducing environment rich in Mg and Si, but with a low Al content. During the thermodynamic evolution process, it undergoes mineral phase transitions and is transformed into minerals such as talc or montmorillonite, which imply different depositional and diagenetic evolutionary paths. In terms of geological applications, sepiolite has an excellent adsorptive behavior, and thus it can efficiently enrich organic matter, providing a basis for the formation of hydrocarbon source rocks with significantly enhanced oil- and gas-generating potential and quality. The diagenetic fluids of the sepiolite layer help promote the transformation of high-energy beach limestone at the edge of a depression into a high-quality dolomite reservoir, thereby giving rise to either of two oil and gas accumulation models: self-generation and self-storage, or lower generation and greater storage. In addition, the thickness and distribution of sepiolite strata inverts undulating paleolandforms and is also an effective indicator of oil and gas reservoir regions, thus providing an important basis for oil and gas exploration. In terms of paleoenvironment, the formation process of sepiolite also records a range of information (e.g., evaporation environment, water level changes, climate evolution and anoxic events) that can be used to reveal major geological events in the region. Conclusions and prospects Sepiolite has shown significant research value in oil and gas exploration, paleogeomorphic reconstruction and paleoenvironmental restoration. Future development trends of sepiolite will include its use in defining paleoenvironmental conditions, enhancing the analytical ability of seismic data on the thickness of sepiolite strata, and developing the exploration of oil and gas in sepiolite strata.
Significance Mires serve as the fundamental environment for coal deposition throughout geological history, offering invaluable insights into Earth’s history, palaeoclimate and environmental evolution, and they are also significant with regards to the global carbon cycle. Numerous geological scholars have conducted a wealth of research on mires. Understanding the research fronts and trends in mire-related studies within coal geology can guide future research. When writing research papers and using professional terminology, scholars may confuse or misuse terminology due to the diverse concepts and English expressions of mires, thus making it particularly crucial to clarify and accurately apply mire-related terminology. Progress Based on data from the Web of Science, common English terms related to “mire” were used as search keywords. A PRISMA flowchart was used to screen out 7479 relevant articles which focused investigations into the temporal evolution and international distribution of mire research in the field of geology. This was further examined using VOSviewer 1.6.20 to conduct keyword co-occurrence analysis on 726 research papers focused on mires in coal geology (selected from the 7479 screened articles). Subsequently, by integrating English definitions of mire-related terms with studies on mires in coal geology, suggestions are offered for simplifying the application of mire-related terminology. Conclusions (1) From 1943 to 2023, a total of 123 nations and regions worldwide participated in mire research, with the year 2000 marking a significant turning point when mire studies gained momentum and became a subject for detailed discussion. Since then, the number of research publications on mires in geology has generally exhibited an upward trend, with scholars from leading research countries engaging in frequent exchanges and academic discussion. Usage frequencies of English mire-related terminology vary between countries, reflecting particular research emphases on different mire types. (2) By integrating meta-analysis, bibliometrics and visualization techniques, research on mires in the field of coal geology is systematically reviewed and summarized. Research themes linked to the topic include coal depositional environments and their evolution, palaeowildfire, atmospheric deposition, carbon accumulation, palaeoclimate and palaeoecology. (3) “Mire” should be considered as a general term for mire-related concepts. When there is a need to emphasize the spatial distribution of mires, “fen” is an appropriate term for low-lying mire, and “bog” should be used instead of “mire” for raised mires. When the ecological or vegetative characteristics of mires need to be highlighted in research, it is recommended to use the words “swamp” or “marsh”. [Prospects] The results offer valuable insights for understanding the deve-lopmental trajectory of international mire research, identifying research fronts of mires in coal geology, and standardizing the application of mire-related terminology in English. Future research on mires in the field of coal geology should actively and effectively utilize big data or machine learning techniques (e.g., simulation modeling, database construction, statistical data analysis, and image recognition classification). Additionally, a multidisciplinary approach integrating geochemical, organic petrological, coal petrological, and mineralogical methods should be systematically employed throughout the research process to ensure comprehensive insights.
Objective The uplift of the Tibetan Plateau is a direct expression of the Earth’s interior geodynamic processes caused by the impact of the collision of the India-Eurasia Plates. Investigating the uplift history is essential to clarify the deformation mechanisms of the continental lithosphere, and remains a central scientific issue in deciphering interactions of the Earth’s multiple spheres. Despite extensive studies, intense debate continues regarding the plateau uplift and expansion. The timing of the uplift in the northern Tibetan Plateau is pivotal for resolving these questions; the Eastern Kunlun Mountains are a crucial geomorphic boundary, since they form the southern margin of the northern plateau and were a critical conduit for the northward propagation of collision-related stresses. The Eastern Kunlun range is an ideal area for studying the uplift processes of the northern Tibetan Plateau, but the timing of their initial uplift remains highly debated. Methods A comprehensive low-temperature thermochronological analysis of the bedrock in the Eastern Kunlun Mountains was conducted to constrain the Cenozoic uplift history. It included integrating the results of 37 low-temperature studies in the region comprising 203 apatite fission track data points and 142 apatite (U-Th)/He data points. Sample selection criteria for low-temperature thermochronology were strictly followed during dataset compilation, and a series of rigorous data-screening strategies were established to minimise disturbances from experimental errors, sample characteristics and complex thermal histories to enhance the accuracy and reliability of the dataset. The analysis involved three steps: (1) the low-temperature thermochronological age distribution was visualised; (2) the relationship between mean track length and age was established; and (3) thermal history modelling results were compiled. Integrating these enabled a detailed, comprehensive low-temperature thermochronology framework to assess the uplift history of the Eastern Kunlun Mountains in the Cenozoic. [Results and Conclusions] Since the Upper Cretaceous, the surface rocks of the Eastern Kunlun Mountains have generally remained in a relatively stable or slowly cooling state within the apatite fission track partial annealing zone and the apatite (U-Th)/He partial retention zone. The Eastern Kunlun Mountains did not form a significant topographic barrier during the Paleogene, and the drainage systems of adjacent basins were likely interconnected. Although the possibility cannot be entirely excluded that sporadic highlands in local areas of the Eastern Kunlun Mountains provided sediment sources for adjacent basins, the data indicates that widespread uplift of the Eastern Kunlun Mountains did not begin to occur until about 20 Ma, when rapid uplift took place causing an estimated rock displacement not less than approximately 2 km relative to the surface, corresponding to the length of the rock column recording Early Miocene apatite (U-Th)/He (22-17 Ma) and apatite fission track (23-15 Ma) age components. This finding provides new evidence for understanding the timing of the paleo-Qaidam Basin disintegration, the paleo-elevation history of the northern Tibetan Plateau in the Early Miocene, and the uplift processes and dynamic mechanisms involved.
Objective Neoproterozoin “Snowball Earth” (Cryogenian) glaciations is a long-standing hot topic in sedimentology. In South China, well-preserved sedimentary records during Cryogenian Period have been found in many places in the Yangtze Block. However, there are relatively few reports on deposits of this time in Kangdian Rift Basin on western margin of the Yangtze Block, and in the rift basin between northern margin of the Yangtze Block and southern margin of the Qingling Orogen. Methods This study focuses on the Cryogenian glacial deposits in the Gangchang-Yuanba section, Hanzhong area, northern margin of the Yangtze Block. Based on the field observations and measurements, zircons were selected from the bottom tuff layer and upper sandstones for U-Pb dating analysis using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Detailed features of the sedimentary rocks and their regional correlation are also discussed. Results Two sets of tillites were identified for the first time within the Neoproterozoic glacial sedimentary rocks in this region, both from a continental glacier. Several layers of sandstone and siltstone are presented between and above the tillite sets. Zircons from the bottom tuff yielded the earliest mean concordant age of (719 ± 11) Ma, indicating the beginning of glaciation in this region. Considering their lithological succession and sedimentary structures, these Cryogenian deposits are thought to have been formed during Sturtian glaciation, corresponding respectively to the Chang’an and Gucheng glaciation periods. The timing of this glaciation event, and the sedimentary associations, are consistent with contemporaneous sediments in the adjacent Zhenba and Chengkou areas, and also show similarities to Sturtian sediments widely distributed in other parts of South China.
Objective The western Hunan region hosts extensive Neoproterozoic marine sedimentary manganese deposits. Manganese (Mn) is a typical redox-sensitive metallic element whose enrichment in sediments is strongly correlated with the redox condition of the bottom water in the basin. A detailed study of the sedimentary redox conditions of such deposits helps to explain their metallogenic mechanisms and the constraints on their marine cycling during the mineralization period, and also provides theoretical support for the assessment of regional mineralization potential. Methods This study involved mineralogical, geochemical and inorganic carbon isotope analyses of 16 manganese ore samples of various grades from the Nanhua System Datangpo Formation in the Minle area, western Hunan. Results Mineralogical and carbon isotope analyses revealed that high-grade (MnO>20%) and medium-grade (10%<MnO<20%) manganese ores consist of predominantly subhedral granular microcrystalline rhodochrosite (grain size <5 μm) and are relatively enriched in light carbon isotope (δ13C=-10.4‰~-8.3‰; n=10). Conversely, low-grade (MnO<10%) manganese ores contain larger- grained (>20 μm) subhedral platy rhodochrosite enriched in heavier carbon isotope (δ13C=-7.4‰~-5.3‰; n=6). Pyrite morphology and element geochemical proxies (Mo, V, Ni concentrations and Ni/Co, V/Cr ratios) indicate that the high-grade manganese ores were deposited in oxic conditions, the medium-grade ore in suboxic conditions, and the low-grade ore in anoxic conditions. Additionally, high-grade ores exhibit geochemical characteristics indicating hydrothermal deposition (e.g., high Eu* values and high Fe/Ti ratios). Conclusions These findings suggest that, in the Minle area of western Hunan, the rhodochrosite in the medium- to high-grade manganese ores was formed as a result of the reaction between Mn oxides with organic matter during diagenesis, whereas in the low-grade manganese ores the rhodochrosite was probably precipitated from Mn2+ and CO in highly alkaline and anoxic conditions. Submarine gas-hydrothermal activity in the deep-water basin of northeastern Guizhou most likely supplied the Mn2+ ions for these manganese deposits; oxidation of bottom water in the basin was the key factor determining manganese enrichment and mineralization in the region.
Objective The Luojiawopeng Formation is a set of purplish red sand and gravel accumulation strata in the Lower Pleistocene Series in the southeastern margin of Songnen plain. The clay mineral analysis of this formation is conducive to understanding the paleoclimate characteristics in this region and defining its stratigraphic age. Methods Whole rock geochemistry, X-ray diffraction (XRD), Scanning electron microscopy (SEM), and High-resolution transmission electron microscopy (HRTEM) analysis of clay minerals in Luojiawopeng Formation were conducted to reveal their composition and transformation characteristics of clay minerals. Comparisons were performed on clay mineral composition between the red clays in the Chinese Loess Plateau and Luojiawopeng Formation. Results The clay mineral composition of Luojiawopeng Formation is dominated by kaolinite (content of 57%⁃73%), followed by illite (ranging from 25% to 41%), and the content of biotite /vermiculite mixed layer minerals is the least (average 1%). Kaolinite shows pseudo hexagonal morphology, and its high degree of euhedral crystallinity indicates its authigenic origin, as does its high illite crystallinity (average 0.55) and illite chemical index (average 0.50). These results, combined with the high clay to quartz ratio, indicate intense weathering characteristics. The transformation process of clay minerals is illite → kaolinite and biotite → biotite /vermiculite mixed layer minerals → kaolinite, which is consistent with the significant kaolinization trend of constant element 4Si-M+-R2+ ternary diagram. combined with the high chemical index of alteration(CIA) and hematite-to-goethite ratio of the formation, this process indicates that these minerals formed in a humid and hot environment with increasingly strong weathering. Conclusions Thus, the Luojiawopeng Formation was likely formed in a humid and hot climate, rather than through moraine accumulation as previously reported, and the stratigraphic chronology of the formation may be in the humid and hot period when the East Asian summer monsoon prevailed before the Early Pleistocene.
Objective Xinying Bay, Hainan province, has retained a relatively complete sedimentary record of marine stratigraphy since the Pleistocene. Owing to its closure and stability, it serves as a good window to reflect the paleoenvironmental changes since the Pleistocene in the northern South China Sea. Methods Based on the analysis of whole rock major elements and Sr-Nd isotopes, the source of sediment material and the evolution of paleoclimate in this area since the Pleistocene were reconstructed, and the driving mechanism was discussed. Results The borehole has three sections from bottom to top. The bottom section, U1, has a relatively low εNd(0) value and a relatively high 86Sr/87Sr value. The middle section, U2, has relatively high ratios of Al/Ti, K/Ti, Fe/Ti, and Mg/Ti. The results of provenance analysis show that the sediments of the borehole come from the intermediate source area, and the U1 section contains more older sedimentary materials, and the Sr-Nd isotope ratio is similar to that of the Red river sediments, whereas U2 and U3 are similar to the Cretaceous-Permian feldspar granite in Hainan Island. The paleo-environmental analysis shows that this region has experienced changes from dry cold to warm wet, and then to dry cold since the Pleistocene. Conclusions The sedimentary period of section U1 corresponds to the coldest period, MIS16, in the Northern Hemisphere, which combined with previous chronological studies, the dry and cold climate, and relatively low sea level, enable the clastic sediments of the Indochina continent to be transported to Xinying Bay. Then, the East Asian summer monsoon strengthened, and the climate changed from cold and dry to warm and humid. As a result, the source area of U2 was dominated by granitic rocks in Hainan Island because the sea level increased. U3 has undergone regional tectonic uplift, and the sedimentary source area is dominated by granite in the island.
Objective Trace elements in modern and ancient dunes from the southern Mu Us Desert record environmental information related to weathering, transportation, and deposition. Analysis of this information facilitates a better understanding of sediment provenance and climatic evolution in the region. Methods Samples of modern and ancient dunes in the southern Mu Us Desert were collected, and the content characteristics and correlations of 14 trace elements including phosphorus (P), lead (Pb), and rubidium (Rb) were analyzed to explore the differences in trace element contents and spatial distribution characteristics among different types of dunes. Results (1) The trace elements in modern and ancient dunes are mainly barium (Ba), strontium (Sr), and phosphorus (P), whereas the contents of arsenic (As), niobium (Nb), and copper (Cu) are relatively low. Their distribution patterns show certain regional characteristics. (2) The trace element contents in fixed dunes are significantly higher than those in mobile dunes owing to the nature of the dunes and vegetation coverage; however, the trace element contents in ancient dunes are higher than those in modern dunes, owing to the influence of sedimentary history, climate change, and special geomorphic positions. (3) The values of Sr/Cu, Rb/Sr, and Sr/Ba in modern and ancient dunes are comparable, indicating that they were formed in similar sedimentary environments. Conclusion There are certain similarities and differences in the trace element contents of modern and ancient dunes and different types of dunes. The changes in trace element contents in ancient dunes can provide clues to the sources of modern dunes to a certain extent. The ratios of trace elements in modern and ancient dunes have certain implications for climate and environmental conditions.