Simple yet extraordinary: Super-polyhedra-built 3D chalcogenide framework of Cs5Ga9S16 with excellent infrared nonlinear optical performance

Simple yet extraordinary: Super-polyhedra-built 3D chalcogenide framework of Cs₅Ga₉S₁₆ with excellent infrared nonlinear optical performance

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Hong Chen^a^,^b^,¹, Mao-Yin Ran^a^,^c^,¹, Sheng-Hua Zhou^a^,^c, Xin-Tao Wu^a^,^b^,^c, Hua Lin^a^,^b^,^c^,^*, Qi-Long Zhu^a^,^b^,^c^,^*

Chinese Chemical Letters | 2023, 34(7) : 107838

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Chinese Chemical Letters | 2023, 34(7): 107838

• Communication •

Simple yet extraordinary: Super-polyhedra-built 3D chalcogenide framework of Cs₅Ga₉S₁₆ with excellent infrared nonlinear optical performance

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Hong Chen^a^,^b^,¹, Mao-Yin Ran^a^,^c^,¹, Sheng-Hua Zhou^a^,^c, Xin-Tao Wu^a^,^b^,^c, Hua Lin^a^,^b^,^c^,^*, Qi-Long Zhu^a^,^b^,^c^,^*

Affiliations

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences (CAS), Fuzhou 350002, China

^b Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China

^c University of Chinese Academy of Sciences, Beijing 100049, China

Published: 2023-07-15 doi: 10.1016/j.cclet.2022.107838

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Abstract

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Non-centrosymmetric chalcogenides are attracting considerable attention as highly promising infrared nonlinear optical (IR-NLO) candidates, but it is challenging to simultaneously achieve sufficient second-harmonic-generation coefficient (d_eff > 0.5 × AgGaS₂) and large energy gap (E_g > 3.5 eV). In this work, a novel ternary chalcogenide, Cs₅Ga₉S₁₆ with an ultra-wide E_g of 4.05 eV, has been successfully obtained. This sulfide belongs to the monoclinic space group Pn (No. 7) with a novel 3D anionic [Ga₉S₁₆]^5– framework that is formed by super-polyhedral [Ga₉S₂₃] units through corner-sharing S atoms. Such a unique crystal structure displays desirable characteristics which indicate a promising IR-NLO candidate: favourable phase-matching feature, sufficient d_eff (0.7 × AgGaS₂), ultrahigh laser-induced damage threshold (31.6 × AgGaS₂) and broad transparent region (0.27−14.96 µm). In addition, systematic theoretical studies and structural analysis suggest that the desirable IR-NLO performances can be attributed to the super-polyhedral building blocks. This finding may provide useful insight into the understanding and designing other high-performance IR-NLO candidates with super-polyhedral-built structures.

Key words

Chalcogenide / IR nonlinear optic / Super-polyhedra-built framework / Wide energy gap / Structure-activity relationship

Cite this Article

Hong Chen, Mao-Yin Ran, Sheng-Hua Zhou, Xin-Tao Wu, Hua Lin, Qi-Long Zhu. Simple yet extraordinary: Super-polyhedra-built 3D chalcogenide framework of Cs₅Ga₉S₁₆ with excellent infrared nonlinear optical performance[J]. Chinese Chemical Letters, 2023 , 34 (7) : 107838 - . DOI: 10.1016/j.cclet.2022.107838

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As the core parts in laser frequency conversion technology, nonlinear optical (NLO) materials have attracted considerable attention because of their capabilities of producing new coherent and tuneable laser source in various ranges [1-5]. To date, the commercially available NLO crystals in IR region are merely ternary chalcopyrite-type AgGaS₂ [7], AgGaSe₂ [6] and ZnGeP₂ [8]. All of them possess sufficient second-harmonic-generation (SHG) coefficient (d_eff) but exhibit several intrinsic problems, such as unfavorable laser-induced damage threshold (LIDT) or unexpected multi-photon absorption caused by small energy gaps (E_g), which seriously hindering their further application in the high-power laser bands. Among all the key conditions for an ideal IR-NLO candidate, achieving concurrently strong d_eff and wide E_g is the most challenging due to the plausible incompatibility [9,10]. Consequently, developing new IR-NLO crystals with improved comprehensive performance are critically needed and of great significance.

Metal chalcogenides with non-centrosymmetric (NCS) crystal structure is known to be the richest source of promising IR-NLO candidates [11-26]. A large number of new IR-NLO materials have been obtained in recent years, but only a few phase-matching (PM) metal chalcogenides that are able to display strong d_eff (> 0.5 × AgGaS₂) and large E_g (> 3.5 eV) simultaneously, such as [Li₂Cs₂Cl][Ga₃S₆] (d_eff = 0.7 × AgGaS₂, E_g = 4.17 eV) [27], Li₄MgGe₂S₇ (d_eff = 0.7 × AgGaS₂, E_g = 4.12 eV) [28], α-Li₂ZnGeS₄ (d_eff = 4.7 × AgGaS₂, E_g = 4.07 eV) [29], Cs₂Cd₂Ga₈S₁₅ (d_eff = 0.5 × AgGaS₂, E_g = 3.98 eV) [30], [Ba₄Cl₂][ZnGa₄S₁₀] (d_eff = 1.1 × AgGaS₂, E_g = 3.85 eV) [31], Li₂CdSiS₄ (d_eff = 1.0 × AgGaS₂, E_g = 3.76 eV) [32], BaLi₂GeS₄ (d_eff = 0.5 × AgGaS₂, E_g = 3.66 eV) [33], SrZnGeS₄ (d_eff = 0.9 × AgGaS₂, E_g = 3.63 eV) [34], Sr₂CdGe₂OS₆ (d_eff = 0.8 × AgGaS₂, E_g = 3.62 eV) [35]. However, the aforementioned compounds are concentrated in complex quaternary or more systems, while simple systems such as ternary compounds are very rare. As far as we know, the existing example is limited to only BaGa₄S₇ (d_eff = 0.9 × AgGaS₂, E_g = 3.54 eV) [36].

In this work, we focus on the ternary A(AE)/M/S (A = alkali metals; AE = alkaline-earth metals; M = group IIIA metal Ga, In or group IVA metal Si, Ge) system. The [MS₄] tetrahedra are the most common NLO-active units in excellent IR-NLO chalcogenides. Meanwhile, the incorporation of highly electropositive A/AE metals in this system may have the additional advantage of increasing the E_g, which may help to enlarge the LIDT once a NCS material is found. Our systematic exploratory efforts have led to the discovery of a new member with 3D framework structure in this family [37-41], namely, Cs₅Ga₉S₁₆. Notably, it shows impressive IR-NLO properties, such as remarkable d_eff (0.7 × AgGaS₂), and the largest E_g (4.05 eV) among known ternary NCS chalcogenides. These findings are quite encouraging for an excellent IR-NLO candidate (d_eff > 0.5 × AgGaS₂ and E_g > 3.5 eV).

The sulfide Cs₅Ga₉S₁₆ is a new ternary phase found within the A–M–Q (A = alkali metals; M = group IIIA metal; Q = S, Se, Te) systems. It was obtained through high-temperature solid-phase method with CsCl as flux (detailed synthesis method can be found in Supporting information). The pure phase of the polycrystalline sample was verified based on the powder X-ray diffraction (XRD) results (Fig. S1 in Supporting information). Moreover, TG-DSC studies reveal that Cs₅Ga₉S₁₆ can be stable up to 1273 K without any obvious endo- or exo-thermal peaks and weight loss (Fig. S2 in Supporting information). Single-crystal XRD suggests that Cs₅Ga₉S₁₆ belongs to the monoclinic space group Pn (No. 7), with a = 9.467(3) Å, b = 9.719(3) Å, c = 18.835(6) Å, V = 1704.3(9) Å³, Z = 2 (Table S1), and features a 3D [Ga₉S₁₆]^5– framework with the charge balancing Cs⁺ ions residing between these voids (Fig. 1). In the structure, 9 crystallographically unique Ga atoms exhibit one type of coordination environment, i.e., the [GaS₄] tetrahedral (Table S2 in Supporting information). The fundamental building block (FBB) is super-polyhedral [Ga₉S₂₃] cluster which is composed of the vertex-sharing S atoms (Fig. 1a). These FBBs are further interlinked with each other via sharing S atoms (i.e., S2, S5, S6 and S12) along the three axial positions to form a 3D framework with Cs⁺ cations located in the cavities (Fig. 1b). As listed in Table S3 (Supporting information), the Ga atoms exhibit normal Ga–S bond length, ranging from 2.219(4) Å to 2.483(5) Å [42-45]. There are 5 crystallographically unique Cs atomic positions with four various coordination geometries, i.e., bi-capped trigonal prism (CN = 8 for Cs1 and Cs2, d_(Cs–S) = 3.415(4)–4.038(4) Å), distorted quadrangular (CN = 10 for Cs3, d_(Cs–S) = 3.398(4)–3.998(4) Å), mono-capped trigonal prism (CN = 7 for Cs4, d_(Cs–S) = 3.562(5)–3.860(4) Å), and tri-capped trigonal prism (CN = 9 for Cs5, d_(Cs–S) = 3.495(4)–3.952(5) Å) (Fig. S3 in Supporting information). To the best of our knowledge, such diverse coordination modes of Cs atoms have been coexisted in Cs₅Ga₉S₁₆ together is unprecedented in Cs-based chalcogenides.

The UV−visible−NIR diffuse reflectance spectrum of Cs₅Ga₉S₁₆ displays one of the widest E_g (i.e., 4.05 eV) among all IR-NLO chalcogenides (Fig. 2a). Such ultra-wide E_g can effectively avoid multi-photon absorptions at the different laser wavelengths, which can obtain a higher LIDT. Moreover, single crystal of Cs₅Ga₉S₁₆ with a typical size of 1.5 × 1.0 mm polished down to ~0.1 mm thickness for the optical transmittance spectra. As given in Fig. 2b, Cs₅Ga₉S₁₆ displays a wide optical transmission from the UV−vis (cut-off wavelength: 0.27 µm) to far-IR band (cut-off wavelength: 14.96 µm). The SHG capability of Cs₅Ga₉S₁₆ was evaluated through the Kurtz-Perry method [46] using 2050 and 1064 nm laser irradiation, respectively, with the famous IR-NLO crystal AgGaS₂ and UV-NLO crystal KDP used for reference. As shown in Figs. 2c and d, the SHG signal tends to attain saturation with the increase of crystal size of sample, which indicates that Cs₅Ga₉S₁₆ possesses PM features and exhibits sufficient d_eff of about 0.7 × AgGaS₂ at 2050 nm and 2.2 × KDP at 1064 nm, respectively. Furthermore, the powder LIDT as another significant parameter for NLO materials was evaluated by single pulse test method at 1064 nm [47]. Consequently, the experimental results of Cs₅Ga₉S₁₆ (ca. 89.1 MW/cm²) is about 31.6 time that of reference AgGaS₂ (ca. 2.82 MW/cm²) [48-50] and about 2.2 time that of reference KDP (ca. 39.8 MW/cm²) [51-53], respectively.

To further investigate the microscopic mechanism of the linear optical and NLO properties of Cs₅Ga₉S₁₆, first-principles calculations were studied. As displayed in Fig. 3a, the calculated band structure reveals that Cs₅Ga₉S₁₆ is an indirect E_g compound with the top of the valence band (VB) and the bottom of the conduction band (CB) occupied the different k-point of the G and F, respectively. As anticipated, the calculated value (E_g = 2.7 eV) is underestimated compared to the experimental value (E_g = 4.05 eV), due to the own defects of the exchange-correlation function [54-56]. To obtain an accurate optical E_g, the calculated E_g via the HSE06 method (4.01 eV) was performed [57,58], which is very close to the experimental result. In addition, the first Brillouin zone with high symmetry points of Cs₅Ga₉S₁₆ is shown in Fig. S5 (Supporting information). The calculated partial densities of states (PDOS) reveal that the Ga-4p and S-3p, states make the main contributions to the lowest of the CB, while the highest of the VB primarily originates from Ga-4s and S-3p states, indicating that the optical E_g of Cs₅Ga₉S₁₆ is mainly due to the 3D [Ga₉S₁₆]^5– framework (Fig. 3b). In addition, the SHG coefficients (d_ij) of Cs₅Ga₉S₁₆ have been also calculated. Based upon the crystal spatial symmetry and the Kleinman restriction [59], there are 6 independent nonzero d_ij, i.e., d₁₁, d₁₂, d₁₃, d₁₅, d₂₄ and d₃₆, respectively (Fig. 3c). Among them, the effective SHG coefficient d_eff at 2050 nm and 1064 nm are about 0.3 × AgGaS₂ and 3.9 × KDP, respectively, which is comparable with the experimental results (Figs. 2c and d). Moreover, the minimum phase matching cut-off wavelength were calculated using the equation n_x(2ω) = n_z(ω). The calculated PM range of the SHG response for Cs₅Ga₉S₁₆ is 760 nm (Fig. 3d) based on the dispersion curves of refractive indices.

The contributions to the principal source of the SHG response from the constituent units were also investigated based on the length-gage formalism technique [60,61]. As displayed in Fig. 4a, it is clear that in the energy regions of VB-1 (−3.0–0.0 eV), CB-1 (3.0–5.0 eV) and CB-3 (6.2–10.0 eV), the d₁₁ values increased most notably as the cut-off energy increased, which contribute mainly to the SHG effect. In other words, the states in the VB-1 section (i.e., the Ga-4p and S-3p states) and those in the CB-1 and CB-3 sections (i.e., the Ga-3s, Ga-4p and S-3p states together with minor S-3s) are mainly responsible for the d₁₁ (Fig. 4b). These results mean that super-polyhedral [Ga₉S₂₃] cluster in 3D [Ga₉S₁₆]^5– framework, contribute to the SHG effect.

In summary, a novel ternary sulfide, Cs₅Ga₉S₁₆, is successfully prepared by a facile solid-state method. It adopts a NCS structure featuring a 3D anionic framework formed by vertex-sharing [Ga₉S₂₃] super-polyhedral FBBs, with the intervening spaces filled by charge-balanced Cs⁺ cations. Significantly, Cs₅Ga₉S₁₆ exhibits excellent IR-NLO performances, such as a favorable PM d_eff (0.7-fold that of the benchmark AgGaS₂), a large LIDTs (31.6-fold that of AgGaS₂), a wide transparent regions (0.27−14.96 µm) and the highest E_g (4.05 eV) at known ternary NCS chalcogenides. Moreover, systematic theoretical analysis indicates that the IR-NLO properties of Cs₅Ga₉S₁₆ mainly originate from the contributions of 3D [Ga₉S₁₆]^5– framework composed of super-polyhedral [Ga₉S₂₃] groups. This finding further extends the study of promising IR-NLO candidates into the simple ternary system and will promote the development of new NCS chalcogenides with wide energy gaps.

Declaration of competing interest

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The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Acknowledgments

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This work was supported by the National Natural Science Foundation of China (Nos. 22175175, 21771179 and 21901246), Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China (No. 2021ZR118), the Natural Science Foundation of Fujian Province (No. 2019J01133) and the Youth Innovation Promotion Association CAS (No. 2022303). The authors thank Prof. Bing-Xuan Li at FJIRSM for helping with the NLO measurements and Prof. Yong-Fan Zhang at Fuzhou University for helping with the DFT calculations.

Supplementary materials

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Supplementary material associated with this article can be found, in the online version, at doi:10.1016/j.cclet.2022.107838.

References

Less

[1]

F.J. Duarte, Tunable Laser Applications, Chapters 2, 9 and 12, CRC Press, Boca Raton, FL, 2008.

[2]

V. Petrov, Prog. Quantum Electron. 44 (2015) 1–106.

[3]

V.A. Serebryakov, E.V. Boiko, N.N. Petrishchev, et al., J. Opt. Technol. 77 (2010) 6–17.

[4]

X.T. Wu, L. Chen, Struct. Bond. (Berlin, Ger.) 145 (2012) 1–42.

[5]

N.L.B. Sayson, T. Bi, V. Ng, et al., Nat. Photonics 13 (2019) 701–706.

[6]

A. Harasaki, K.J. Kato, Appl. Phys. 36 (1997) 700–703.

[7]

G.C. Catella, L.R. Shiozawa, J.R. Hietanen, et al., Appl. Opt. 32 (1993) 3948–3951.

[8]

G.D. Boyd, E. Buehler, F.G. Storz, Appl. Phys. Lett. 18 (1971) 301–304.

[9]

H. Chen, W.B. Wei, H. Lin, et al., Coord. Chem. Rev. 448 (2021) 214154.

[10]

K. Wu, S.L. Pan, Coord. Chem. Rev. 377 (2018) 191–208.

[11]

I. Chung, M.G. Kanatzidis, Chem. Mater. 26 (2013) 849–869.

[12]

H. Lin, L. Chen, L.J. Zhou, et al., J. Am. Chem. Soc. 135 (2013) 12914–12921.

[13]

L. Kang, M.L. Zhou, J.Y. Yao, et al., J. Am. Chem. Soc. 137 (2015) 13049–13059.

[14]

H. Lin, Y.Y. Li, M.Y. Li, et al., J. Mater. Chem. C 7 (2019) 4638–4643.

[15]

S.P. Guo, Y. Chi, G.C. Guo, Coord. Chem. Rev. 335 (2017) 44–57.

[16]

P.F. Gong, F. Liang, L. Kang, et al., Coord. Chem. Rev. 380 (2019) 83–102.

[17]

M.Y. Li, Z.J. Ma, B.X. Li, et al., Chem. Mater. 32 (2020) 4331–4433.

[18]

M.Y. Ran, Z. Ma, H. Chen, et al., Chem. Mater. 32 (2020) 5890–5896.

[19]

L. Gao, J.B. Huang, S.R. Guo, et al., Coord. Chem. Rev. 421 (2020) 213379.

[20]

W.K. Wang, D.J. Mei, F. Liang, et al., Coord. Chem. Rev. 421 (2020) 213444.

[21]

H. Lin, W.B. Wei, H. Chen, et al., Coord. Chem. Rev. 406 (2020) 213150.

[22]

D. Mei, W. Cao, N. Wang, et al., Mater. Horiz. 8 (2021) 2330.

[23]

W. Wang, D. Mei, S. Wen, et al., Chin. Chem. Lett. 33 (2022) 2301–2315.

[24]

F. Hou, D. Mei, Y. Zhang, et al., J. Alloys Compd. 904 (2022) 163944.

[25]

M.M. Chen, S.H. Zhou, W.B. Wei, et al., ACS Mater. Lett. 4 (2022) 1264–1269.

[26]

H. Chen, M.Y. Ran, W.B. Wei, et al., Coord. Chem. Rev. 470 (2022) 214706.

[27]

B.W. Liu, X.M. Jiang, B.X. Li, et al., Angew. Chem. Int. Ed. 132 (2020) 4886–4889.

[28]

A. Abudurusuli, J.B. Huang, P. Wang, et al., Angew. Chem. Int. Ed. 60 (2021) 24131–24136.

[29]

J.H. Zhang, D.J. Clark, J.A. Brant, et al., Chem. Mater. 32 (2020) 8947–8955.

[30]

L.Q. Yang, X.M. Jiang, S.M. Pei, et al., ACS. Appl. Mater. Interfaces 14 (2022) 4352.

[31]

H. Chen, Y.Y. Li, B.X. Li, et al., Chem. Mater. 32 (2020) 8012.

[32]

J.H. Zhang, D.J. Clark, J.A. Brant, et al., Chem. Mater. 32 (2020) 8947.

[33]

K. Wu, B.B. Zhang, Z.H. Yang, et al., J. Am. Chem. Soc. 139 (2017) 14885.

[34]

Q.Q. Liu, X. Liu, L.M. Wu, et al., Angew. Chem. Int. Ed. 61 (2022) e202205587.

[35]

M.Y. Ran, S.H. Zhou, B. Li, et al., Chem. Mater. 34 (2022) 3853–3861.

[36]

X.S. Lin, G. Zhang, N. Ye, et al., Cryst. Growth Des. 9 (2009) 1186.

[37]

V.V. Atuchin, F. Liang, S. Grazhdannikov, et al., RSC Adv. 8 (2018) 9946–9955.

[38]

S.F. Li, X.M. Jiang, B.W. Liu, et al., Chem. Mater. 29 (2017) 1796–1804.

[39]

M.Y. Ran, Z. Ma, X.T. Wu, et al., Inorg. Chem. Front. 8 (2021) 4838–4845.

[40]

M.M. Chen, S.H. Zhou, W. Wei, et al., Inorg. Chem. 60 (2021) 10038–10046.

[41]

W.F. Chen, X.M. Jiang, S.M. Pei, et al., Sci. China. Mater. 66 (2023) 740–747.

[42]

H. Lin, L. Chen, J.S. Yu, et al., Chem. Mater. 29 (2017) 499–503.

[43]

M.Y. Li, B.X. Li, H. Lin, et al., Chem. Mater. 31 (2019) 6268–6275.

[44]

M.M. Chen, S.H. Zhou, W.B. Wei, et al., Adv. Opt. Mater. 10 (2022) 202102123.

[45]

Y.Y. Li, W.J. Wang, H. Wang, et al., Cryst. Grow. Des. 19 (2019) 4172–4192.

[46]

S.K. Kurtz, T.T. Perry, J. Appl. Phys. 39 (1968) 3798–3813.

[47]

M.J. Zhang, X.M. Jiang, L.J. Zhou, et al., J. Mater. Chem. C 1 (2013) 4754–4760.

[48]

M.M. Chen, Z. Ma, B.X. Li, et al., J. Mater. Chem. C 9 (2021) 1156–1163.

[49]

C. Liu, S.H. Zhou, Y. Xiao, et al., J. Mater. Chem. C 9 (2021) 15407–15414.

[50]

Y. Xiao, M.M. Chen, Y.Y. Shen, et al., Inorg. Chem. Front. 8 (2021) 2835–2843.

[51]

Y.X. Zhang, B.X. Li, H. Lin, et al., J. Mater. Chem. C 7 (2019) 6217–6221.

[52]

H.D. Yang, M.Y. Ran, S.H. Zhou, et al., Chem. Sci. 13 (2022) 10725–10733.

[53]

Y.F. Shi, Z. Ma, B.X. Li, et al., Mater. Chem. Front. 6 (2022) 3054–3061.

[54]

K.J. Burke, Chem. Phys. 136 (2012) 150901.

[55]

N.E. Christensen, A. Svane, E.L. Peltzery Blancá, Phys. Rev. B: Condens. Matter Mater. Phys. 72 (2005) 014109.

[56]

K. Govaerts, R. Saniz, B. Partoens, et al., Phys. Rev. B: Condens. Matter Mater. Phys. 87 (2013) 235210.

[57]

J. Heyd, G.E. Scuseria, M. Ernzerhof, J. Chem. Phys. 118 (2003) 8207.

[58]

F. Ge, B.H. Li, P. Cheng, et al., Angew. Chem. Int. Ed. 61 (2022) e202115024.

[59]

D.A. Kleinman, Phys. Rev. 126 (1962) 1977–1979.

[60]

C. Aversa, J.E. Sipe, Phys. Rev. B 52 (1995) 14636–14645.

[61]

S.N. Rashkeev, W.R.L. Lambrecht, B. Segall, Phys. Rev. B 57 (1998) 3905–3919.

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Year 2023 volume 34 Issue 7

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doi: 10.1016/j.cclet.2022.107838

Receive Date：2022-07-25
Online Date：2025-11-21
Published：2023-07-15

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Received：2022-07-25
Revised：2022-08-29
Accepted：2022-09-20

Affiliations

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences (CAS), Fuzhou 350002, China

^b Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China

^c University of Chinese Academy of Sciences, Beijing 100049, China

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表12种不同金属材料的力学参数

科 Family	属数 Number of genus	种数 Number of species	占总种数比例 Percentage of total species (%)	属 Genus	种数 Number of species	占总种数比例 Percentage of total species (%)
鹅膏菌科Amanitaceae	2	11	5.26	鹅膏菌属 Amanita	10	4.78
小菇科 Mycenaceae	2	12	5.74	丝盖伞属 Inocybe	5	2.39
多孔菌科 Polyporaceae	8	14	6.70	蜡蘑属 Laccaria	5	2.39
红菇科 Russulaceae	3	23	11.00	小皮伞属 Marasmius	6	2.87
				小菇属 Mycena	11	5.26
				光柄菇属 Pluteus	5	2.39
				红菇属 Russula	17	8.13
				栓菌属 Trametes	5	2.39

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Fig. 1. Illustration of the structure of Cs₅Ga₉S₁₆: (a) Coordination geometry of super-polyhedral [Ga₉S₂₃] FBB with the atom number outlined. (b) 3D framework structure of Cs₅Ga₉S₁₆ viewed along the a direction with the unit cell marked (super-polyhedral [Ga₉S₂₃] cluster is outlined by a dashed area).

Fig. 2. Experimental results of Cs₅Ga₉S₁₆: (a) UV−visible−NIR diffuse reflectance spectrum (inset: polished single crystal wafers). (b) Optical transmisission from UV−vis to IR band. (c, d) SHG signals versus particle size under 2050 nm and 1064 nm Q-switch laser, respectively.

Fig. 3. Theoretical calculation results of Cs₅Ga₉S₁₆: (a) Electronic band structure; (b) PDOS (the Fermi level (E_F) is set at 0.0 eV); (c) Frequency-dependent SHG coefficients (d_ij); (d) The calculated dispersion of the refractive indices and the shortest type-Ⅰ PM cut-off wavelength.

Fig. 4. Theoretical analysis of the NLO source: (a) Cut-off-energy-dependent variation of static coefficient d₁₁; (b) Charge density maps in the VB-1, CB-1 and CB-3 regions along the bc plane.

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